Chapter 12 Flashcards

(57 cards)

1
Q

theoretical definition of oxidization

A

the loss of electrons, results in an increase in ON

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2
Q

theoretical definition of reduction

A

the gain of electrons, results in a decrease in ON

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3
Q

operational definition of oxidization

A

the reaction with molecular oxygen

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4
Q

operational definition of reduction

A

the extraction of metals from metal ore

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5
Q

oxidizing agent definition

A

reactant being reduced, causing another reagent to be oxidized

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6
Q

reducing agent

A

reactant being oxidized, causing another reagent to be reduced

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7
Q

redox reactions happen betweeen a ______ and a ______

A

oxidizing and reducing agent

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8
Q

in redox reactions electrons are _____

A

gained by one atom or ion and lost by another

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9
Q

oxidization numbers definition

A

hypothetical numbers used to determine the degree of oxidization of an atom

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10
Q

redox reactions involve ____ of electrons

A

transfer

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11
Q

what indicates a redox reaction

A

a change in an element’s ON

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12
Q

steps for determining if reactions are redox or non-redox

A

1) assign ON’s

2) determine if reactions are redox or non redox
- non redox=no change in ON
- redox=change in ON

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13
Q

definition of spontaneous redox reaction

A

takes place without the input of electricity

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14
Q

if OA is above RA, the reaction is _______

A

spontaneous/ does happen

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15
Q

if OA is below RA, the reaction is _____

A

non-spontaneous/ doesn’t happen

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16
Q

oxidizing agents are on the ___ side of the redox table

A

left

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17
Q

reducing agents are on the ___ side of the table

A

right

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18
Q

the SOA is at the ____ of the table

A

top

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19
Q

the SRA is at the _____ of the table

A

bottom

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20
Q

the WOA is at the ____ of the table

A

bottom

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21
Q

the WRA is at the ____ of the table

A

top

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22
Q

copy out reduction reactions from ____ to ____

A

left to right (regular)

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23
Q

copy out oxidization reactions from ___ to ___

A

right to left (opposite)

24
Q

steps for determine if a redox reaction is spontaneous or non spontaneous

A

1) determine OA and RA by assigning oxidization numbers

2) consult redox table to determine or spontaneous or not
- spontaneous= OA is above RA
- non spontaneous= OA is below RA

25
steps for building a redox table
1) determine OA and RA of each equation by assigning oxidization numbers - metals are always RA 2) place the OA and RA in each equation relative to each other on the table - each OA and RA has a corresponding element
26
what is an oxidization half reaction
separating a redox reaction into its oxidization component
27
what is a reduction half reaction
separating a redox reaction into its reduction component
28
oxidization half reactions have electrons on ____ side
product
29
reduction half reactions have electrons on ____ side
reactant
30
balancing steps
1) write half reactions 2) balance any atoms other than H and O 3) balance oxygen by adding H2O 4) balance hydrogen by adding H+ 5) balance any charges by adding electrons 6) multiply half reaction by LCM to cancel out electrons 7) add the balance half reactions 8) cancel out any ions present on both sides 9) add spectator ions back in if they were removed when writting half reaction
31
steps for balancing equations using half reactions from data booklet (and what format is this question usually in)
usually in all word format 1) list all things you have acidified/acid=H+ solution=H2O 2) find SOA (consult table) and copy out half reaction 3) find SRA (consult table) and copy out half reaction 6) continue steps for regular balancing
32
what do you make sure of when copying out half reaction
that you’re copying them out in the CORRECT direction
33
disproportionation definition
sometimes some atoms of an element can undergo oxidization while some atoms of the same element undergo reduction
34
steps for determine which element undergoes disproportionation
1) assign ON’s | 2) determine which element is being both oxidized and reduced
35
step for balancing disproportionation reactions:
1) assign ON’s 2) determine which element is being both oxidized and reduced 3) start and finish steps for regular balancing
36
titration definition
process used to determine the concentration of an unknown solution
37
titrant definition
solution of KNOWN concentration
38
sample definition
solution of UNKOWN concentration
39
titration process
a solution of known concentration (titrant) is added slowly to the solution of unknown concentration (sample) until the reaction is complete
40
endpoint definition
point when you observe a sudden change in colour
41
what is the endpoint dependent on
the indicator in acid-base titration
42
equivalence point definition
point where the chemical amount of the titrant is stoichiometrically equal to the chemical amount present in the solution of unknown concentration
43
acid-base indicator definition
a compound that changes colour over a given pH range
44
the ___ is in the buret (titrant or sample)
titrant
45
the ___ is in the erlenmeyer flask (titrant or sample)
sample
46
where is the stopcock (relative to the buret)
at the bottom of the buret
47
what is the retort stand
the thing holding everything up
48
where is the buret clamp
attached to the retort stand, hold the buret
49
why do we commonly us OA/RA’s that change colour themselves in redox titrations?
so we don’t have to add an additional indicator
50
photosynthesis equation
6 CO2(g)+ 6 H2O(l) + energy —> C6H12O6(s) + 6 O2(g)
51
cellular respiration equation
C6H12O6(s) + 6 O2(g) —-> 6 CO2(g) + 6 H2O(l) + energy
52
what is the OA in cellular respiration
oxygen
53
what is the RA in cellular respiration
sugar
54
what is the OA in photosynthesis
CO2
55
what is the RA in photosynthesis
water
56
increase in ph ( in terms of hydrogen ions and acidity)
taking hydrogen ions and converting them to water (H+ on reactant side) becomes LESS acidic
57
decrease in ph ( in terms of hydrogen ions and acidity)
when your producing hydrogen ions becomes MORE acidic