Chapter 11- Solutions and Colloids Flashcards
solution
homogeneos mixture of 2 mor more substances
solvent
component present in high concentration
sulute
component prensent in low concentration
strong electrolytes
completely dissociate into ion
weak electrolytes
partiall dissociate into ions
nonelectrolytes
stay as intact molecules
solubility
of a solute in a particular solvent is the maximum concentration that may be archieved under given condition when the dissolution process at dynamic equilibrium
saturated solution
a solution containing solute that is equal to solubility ; maximum concentration of solute possible for a given tem an pressure
(additional solu will not dissolve)
unsaturated solution
a solution containing less solute than solubility
more solute will dissolve
supersaturated solution
a solution containing of concentration that exeeds solubility( a nonequilibrium state)
use curve to predid if saturated
on the curve
use curve to predict if unsaturated
below the curve
use curve to predict if supersaturated
above the curve
solubility dependence for a solid
if temp increase= solubility increase
solubility dependence of temp on a gas
if temp increase= solubilty decreae
solubility dependence of pressure on a gas
if pressure increase= solubility increase
colligative properties
property of a solution that depends only on the concentration of a silute species, not the type of particle
4 types of colligative properties
- vapor pressure lowweing
- freexing point depression
- boiling point elevation
- osmotic pressure
colligative properties are similar in that they all
depend on the number of solute particles in solution
electrolyte
a substance that dissociates into ions when dissolved in water
nonelectrolyte
a compound that does not dissociate into ions when dissolved in water
vant hoff factor
(i) the ratio of moles of particles in a solution to the moles of formula int disolved in the solution
nonelectrolyte van hof factor is always
1
formula for (i) vant hoff factor
moles particles in a solution/ moles of formula unti dissolved
raoults law
the partial pressure exerted by any component of an ideal solution is equal to the vapor pressure of the pur component multipled by its mole fration in the solution
freezing point depression
lowering of the freesing point of a liquid by adding a solute
boiling boint elevation
elevation of the boiling point of a lkiquid by adding a solute
osmosis
the diffusion of solvent from a solution of lower solute concentration to one of higher solute concentration through a semipermeable membrane
initial
a semipermeable membrane selectively allows only solvent (small size) to pass but not the solute (big size).
at equilibrium
he solution level on the left side rises, while the water level on the right side falls.
osmotic pressure
is the opposing pressure required to prevent the movemtn of solvent molecules though a semipermeable membrane