Chapter 11 Intermolecular Forces and Phase Changes Flashcards
Dipole-Dipole Force
Intermolecular force between two polar molecules. The partial positive charge
on one molecule is attracted to the partial negative charge on the other molecule
London Dispersion Force
Intermolecular force caused by fluctuations in the electron distribution
within atoms and molecules. All atoms or molecules experience London dispersion forces
Instantaneous Dipole
Partial positive and partial negative charges formed by temporary, random
fluctuations in electron distribution
Induced Dipole Moment
Partial positive and partial negative charges formed as the result of an
instantaneous dipole on a neighboring atom or molecule
Hydrogen Bonding
Hydrogen bonds occur between a hydrogen that is bonded to F, N, or O and the
lone pair of electrons of an F, N, or O atom in another molecule
Hydrogen Bond Donor
A hydrogen atom directly bonded to a F, O, or N atom
Hydrogen Bond Acceptor
An electronegative F, O, or N atom with a lone pair of electrons
Sublimation
Phase change from a solid to a gas.
Condensation
Phase change from a gas to a liquid.
Deposition
Phase change from a gas to a solid
Phase change from a gas to a solid
depostition
Triple Point
Conditions under which all three states (solid, liquid, and gas) are equally stable and in
equilibrium
Critical Point
Temperature and pressure above which a supercritical fluid exists
Supercritical Fluid
A substance that has the properties of both a liquid and a gas. Supercritical fluids
exist at high temperatures and pressures
Surface Tension
The tendency of liquids to minimize their surface area
Viscosity
Resistance of a liquid to flow
Capillary Action
Ability of liquids to flow up a narrow tube against the force of gravity.
Larger atoms or molecules have a ______ London dispersion force than smaller atoms or molecules
with a similar shape
stronger
Spherical molecules have a __________ London dispersion force than linear molecules with a similar size
weaker
Explanation: they have a smaller surface area for between molecules.
True or False: hydrogen bonding can occur between two different molecules
True
True or False: a molecule must have a H atom bonded directly to N, O, or F to participate in hydrogen
bonding.
false
List intermolecular strength in order of increasing strength
London dispersion forces, dipole-dipole forces, Hydrogen Bond
What is the melting/freezing point of water?
0 degrees C
What is the boiling/condensation point of water?
100 degrees C