Chapter 11: Gases Flashcards
List the five postulates of kinetic-molecular theory of gases
- Particles are not attracted to each other or its container
- Are always in motion and moves in a straight line but random movement
- When they strike each other, energy is conserved, not lost
- Kinetic energy increases when temperature increases
- the temp is the average kinetic energy of the particles
Explain the physical properties of gases using concepts from the kinetic-molecular
theory
Gases are compressible, the particles can be moved closer together. The shape equals the shape of their container, expand to fill the whole container. Gasses have low density
Define (gas) pressure.
frequency that the gases strike the surface, the wall of the container.
Remember the conversion between units of pressure.
1 atm = 760 mm Hg = 760 torr.
These are exact conversions, so they will not influence the number of significant figures.
Remember the USA measure of pressure.
atmospheric pressure as inches of
mercury (in Hg) and to measure tire pressure as pounds per square inch (psi).
Remember the conversion factor used to convert between the Celsius and Kelvin
temperature scales.
(EC + 273 = K or K – 273 = EC)
For any gas calculation question using temperature (see below), only Kelvin temperature
is used. Explain the reason.
zero on the kelvin scale refers to stop of molecular motion
List the four factors that affect the behavior (activity) of gases.
Pressure, temperature, volume, and number of particles (mol)
The relationships between two variables associated with gases are described by individual gas laws
Boyle’s Law: P x V = k
Charles’ Law: V/T = k
Gay Lussac’s Law: P/T = k
Avogadro’s Law: V/n = k
Remember the combined gas law equation with eight variables.
(P1 x V1) / (T1 x n1) = (P2 x V2) / (T2 x n2). When a variable in condition 1 does not change in condition 2
Remember the ideal gas law
PV - nRT when R is constant = (0.0821 x L) / (mol x k)
Remember Dalton’s Law of Partial Pressures
the total pressure in a container is equal to the sum of the individual gas pressures. The different gas pressures are proportional to the total amount of gas
Explain how the gas pressure in a container is affected
Pressure decreases when volume increases. Pressure increases when temperature increases. Pressure increases when number of molecules increase
Explain how the gas pressure in a container is affected by changes in container volume
decreasing volume increases gas pressure
Explain how the gas pressure in a container is affected by changes in temperature
increasing temperature increases gas pressure