Chapter 11- Basic concepts of organic chemistry Flashcards

1
Q

What is a hydrocarbon?

A

A compound containing only hydrogen and carbon.

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2
Q

What is an aliphatic hydrocarbon.

A

Carbon atoms are joined to each other in unbranched (straight) or branched chains or non-aromatic rings.

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3
Q

What is an alicyclic hydrocarbon.

A

Carbon atoms are joined to each other in ring (cyclic) structures, with or without branches.

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4
Q

What is an aromatic hydrocarbon.

A

Some or all of the carbon atoms are found in a benzene ring.

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5
Q

What is a saturated hydrocarbon?

A

Single bonds only.

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6
Q

What is an unsaturated hydrocarbon?

A

Contains carbon to carbon multiple bonds.

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7
Q

What is a homologous series?

A

A family of compounds with similar chemical properties whose successive members differ by the addition of a -CH2- group.

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8
Q

What is a functional group?

A

The part of an organic molecule that is largely responsible for the molecules chemical properties.

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9
Q

Describe each of the following aliphatic hydrocarbons…
alkanes
alkenes
alkynes

A

alkanes- containing single carbon to carbon bonds
alkenes- containing at least one double carbon to carbon bond
alkynes- containing at least one triple carbon to carbon bond

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10
Q

Describe how to name aliphatic alkanes.

A
  • have the suffix -ane
  • identify the longest continuous chain of carbon atoms
  • identify the side chains known as alkyl groups
  • add numbers before any alkyl groups to show the position of the group
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11
Q

How to name alicylic alkanes.

A

Same rules apply as when naming alicylic alkanes…

  • have the suffix -ane
  • identify the longest continuous chain of carbon atoms
  • identify the side chains known as alkyl groups
  • add numbers before any alkyl groups to show the position of the group

Then add the prefix cyclo- e.g. cyclopentane

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12
Q

How to name alkenes.

A
  • have the suffix -ene
  • identify the longest continuous chain of carbon atoms
  • identify the side chains known as alkyl groups
  • add numbers before any alkyl groups to show the position of the group
  • the position of the C=C bond in the chain must be stated using numbers before the suffix
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13
Q

Name the prefix/suffix associated with the following types of compounds…

  • alkene
  • alcohol
  • haloalkane
  • aldehyde
  • ketone
  • carboxylic acid
A
  • alkene
    suffix: -ene
  • alcohol
    prefix: hydroxy-
    suffix: -ol
  • haloalkane
    prefix: chloro-, bromo-, iodo-
  • aldehyde
    suffix: -al
  • ketone
    suffix: -one
  • carboxylic acid
    suffix: -oic acid
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14
Q

Side chains are named in what order?

A

alphabetical

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15
Q

What is the molecular formula?

A

Shows the number and type of atoms of each element present in a molecule.
It does not show how atoms are joined together.

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16
Q

What is the empirical formula?

A

The simplest whole number ratio of the atoms of each element present in a compound.

17
Q

What is the general formula?

A

The simplest algebraic formula for any member of a homologous series. The general formula can be used to generate the molecular formula for any member of that homologous series.

18
Q

What is the displayed formula?

A

It shows the relative positioning of all of the atoms in a molecule and the bonds between them.

19
Q

What is the structural formula?

A

The smallest amount of detail necessary to show the arrangement of the atoms in a molecule. It clearly shows which groups are bonded together. For example the structural formula of propane is CH3CH2CH3

20
Q

What is the skeletal formula?

A

It is a simplified organic formula. You remove…
- all of the carbon and hydrogen labels from carbon chains
- any bonds to hydrogen atoms
This just leaves a carbon skeleton and any functional groups
In skeletal formula…
- a line represents a single bond
- an intersection of two lines represents a carbon atom
- the end of a line represents a -CH3 group