Chapter 11 Basic concepts of organic chemistry Flashcards
Why is carbon so special?
It has 4 electrons in outer shell
it makes 4 covalent bonds.
Either single,double, triple
they can bond with other carbons to make long chains
Hydrocarbons
contains hydrogen and carbon
Saturated and Unsaturated
saturated - every carbon has single bonds only
Unsaturated - has double bond or triple
Homologous series
a family of compounds with similar chemical properties and have a general formula
Functional groups
is the part of the molecule that is responsible for the chemical properties.
three classifications of hydrocarbons
aliphatic - carbon atoms are joined to each other in unbranched or branched chains
alicyclic - carbon atoms joined together in ring structures
aromatic - found in a benzene ring
three types of aliphatic homologous series
alkanes - contains single carbon-carbon bonds
alkenes - contains one double carbon-carbon bond
alkynes - contains one triple carbon-carbon bond
Skeletal formula
is simplified organic formula
you remove all fo the C and H labels and any bonds to H atoms.
a line represents a single bond.
the end of a line represents CH3.
Structural isomers
compounds withe same formula but different structures.
Isomers with same functional group
the functional group can be at different positions along the carbon chain.
Isomers with different functional groups
sometimes two molecules with different functional groups may have same formila. Aldehydes and ketones do.
Homolytic fission
Each atom now has a single unpaired electrons.
An atom or groups of atoms with an unpaired electron is called a radical.
Heterlytic fission
The atom that takes both electrons becomes a negative ion.
The atom that does not take becomes a positive ion.
Curly arros
they show the movement of a pair of electrons.
Types of reactions
Addition - two reactants join together to form one product.
Substitution - an atom or group of atoms is replaced by a different atom or group of atoms
Elimination - The removal of a small molecule from a large one.