Chapter 11 - Basic Concepts of Organic Chemistry Flashcards

1
Q

What is the difference between a saturated and an unsaturated hydrocarbon?

A

A saturated hydrocarbon only has single bonds, whereas an unsaturated hydrocarbon contains multiple bonds.

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2
Q

What is a homologous series?

A

A family of compounds with similar chemical properties whose successive members differ by the addition of a
-CH2 group

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3
Q

What is a functional group?

A

The part of an organic molecule that is responsible for the molecule’s chemical properties.

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4
Q

What is an aliphatic hydrocarbon?

A

Carbon atoms are joined to each other in a straight chain, or branched chains, or non-aromatic chains.

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5
Q

What is an alicyclic hydrocarbon?

A

Carbon atoms are joined to each other in a cyclic structure.

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6
Q

What is an aromatic hydrocarbon?

A

Some or all of the carbon atoms are in a benzene ring.

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7
Q

What is the difference between alkanes, alkenes and alkynes?

A
Alkanes = Single carbon-carbon bonds
Alkenes = One or more double carbon-carbon bond
Alkynes = One or more carbon-carbon triple bond
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8
Q

What are the names of the first 10 alkanes?

A
Methane
Ethane
Propane
Butane
Pentane
Hexane
Heptane
Octane
Nonane
Decane
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9
Q

What is the functional group and suffix for an aldehyde?

A

CHO

-al

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10
Q

What is the functional group and suffix for an ketone?

A

-C(C=O)C-

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11
Q

What is a general formula?

A

The simplest algebraic formula for any member of a homologous series.

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12
Q

What is displayed formula?

A

Shows the relative positioning of all of the atoms in a molecule and the bonds.

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13
Q

What is structural formula?

A

Shows which groups are bonded together.

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14
Q

What is a structural isomer?

A

Compounds with the same molecular formula but different structural formula.

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15
Q

What is homolytic fission?

A

When a covalent bond breaks, each of the bonded atoms takes one electron from the bonded pair to form 2 radicals.

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16
Q

What is formed after homolytic fission?

A

2 atoms with an unpaired electron.

These atoms are called free radicals.

17
Q

What is heterolytic fission?

A

When a covalent bond breaks, one of the bonded atoms takes both electrons from the electron pair.

18
Q

What is formed after heterolytic fission?

A

A positive and a negative ion

19
Q

What are curly arrows used to show?

A

The movement of electron pairs when bonds are being broken or made.

20
Q

What is an addition reaction?

A

2 reactants join together to form 1 product

21
Q

What is a substitution reaction?

A

An atom or group of atoms is replaced by another atom or group of atoms

22
Q

What is an elimination reaction?

A

The removal of a small molecule from a larger one.

1 reactant breaks down into 2 products

23
Q

Where must a curly arrow start from?

A

A covalent bond, a lone pair of electrons, or a negative charge