Chapter 11 Flashcards

1
Q

Organic chemistry

A

study of the structure,properties, composition, reactions and preparation of carbon containing compounds

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2
Q

Hydrocarbon

A

is a compound consisting of hydrogen and carbon only

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3
Q

Saturated

A

Contain single carbon-carbon bonds only

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4
Q

Molecular formula

A

The formula which shows the actual number of each type of atom

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5
Q

Empirical formula

A

: shows the simplest whole number ratio of atoms of each element in the compound

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6
Q

General formula

A

algebraic formula for a homologous series e.g. CnH2n

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7
Q

Structural formula

A

shows the minimal detail that shows the arrangement of atoms in a
molecule, eg for butane: CH3CH2CH2CH3 or CH3
(CH2)2CH3

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8
Q

Displayed formula

A

show all the covalent bonds present in a molecule

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9
Q

Skeletal formula

A

shows the simplified organic formula, shown by removing hydrogen atoms from alkyl chains,
leaving just a carbon skeleton and associated functional Groups.

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10
Q

Aliphatic:

A

a compound containing carbon and hydrogen joined together in straight chains, branched chains or
non-aromatic rings

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11
Q

Alicyclic

A

an aliphatic compound arranged in non-aromatic rings with or without side

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12
Q

Aromatic

A

: a compound containing a benzene ring

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13
Q

Unsaturated

A

The presence of multiple carbon–carbon bonds, including C=C, C≡C and aromatic ring

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14
Q

features ALSO

Homologous series

A

are families of organic compounds with the same functional
group and same general formula.
*They show a gradual change in physical properties (e.g. boiling point).
* Each member differs by CH2
from the last.
* same chemical properties.

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15
Q

Functional group

A

is an atom or group of atoms which when present in different molecules causes them to have similar chemical properties

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16
Q

-ane

17
Q

ene

18
Q

alcohol/ol

19
Q

Haloalkanes

20
Q

Aldehydes

21
Q

Ketones

22
Q

carboxylic acids

23
Q

Esters

24
Q

when do you remove the -E in alkane

A

when the suffix starts with a vowel

25
when do we use hydroxy-:
If the compound has an –OH group in addition to another functional group with a higher priority. The priority group gets the suffix ending and the OH can be named with the prefix
26
Order of priority | aldehydes, ketones, alkenes, carboxylic acids, alcohols,halogenoalkanes
Carboxylic acids>aldehydes>ketones>alcohols>alkenes>halogenoalkanes
27
An aldehyde’s name ends in
–al
28
Structural isomers
: same molecular formula different structures (or structural formulae)
29
Structural isomerism can arise from
*Chain isomerism *Position isomerism *Functional group isomerism
30
Chain isomers
Compounds with the same molecular formula but different structures of the carbon skeleton
31
Position isomers:
Compounds with the same molecular formula but different structures due to different positions of the same functional group on the same carbon skeleton
32
Functional group isomers:
Compounds with the same molecular formula but with atoms arranged to give different functional groups
33
Homolytic fission:
each atom gets one electron from the covalent bond produces two free radicals represented by a .
34
Heterolytic fission:
(one atom gets both electrons) produces ions ## Footnote two headed arrow shows movement of pair of electrons
35
Free radical
is a reactive species which possess an unpaired electron