Chapter 10: : Precision and Accuracy of Chemical Analyses Flashcards
Measurement data can only give us an ____ of the “true” value
Estimate
In order to improve the reliability and to obtain information about the variability of results
Replicates
How many replicates are usually needed to carried out an entire analytical procedure
Several (often two to five) portions (replicates)
The best estimate of the true value
Central value for the set
- The most widely used measure of central value
- also called the arithmetic mean or the average
Mean
is the middle result when replicate data are arranged in increasing or decreasing order
Median
indicates the closeness of the measurement to the true or accepted value and is expressed by the error
Accuracy
is a measure of how close a series of measurements are to one another
Precision
Three terms widely used to describe the precision
- standard deviation
- variance
- coefficient of variation
the difference between the experimental value and the accepted value.
Error
is the correct value based on reliable references
Accepted value
is the value measured in the lab.
Experimental value
Error formula
Error= Experimental value - accepted value
where xi is a measurement of the quantity and xt is the true or accepted value of the quantity.
Absolute error
Absolute error formula
E= xi - xt