Chapter 10 - Liquids and Solids Flashcards

1
Q

Adhesive Force

A

Force of attraction between molecules of different chemical identities

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2
Q

Amorphous solid

A

(aka: noncrystalline solid)

Solid in which the particles lack an ordered internal structure

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3
Q

Boiling point

A

Temperature at which the vapor pressure of a liquid equals the pressure of the gas above it

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4
Q

Bragg equation

A

Equation that relates the angles at which x-rays are diffracted by the atoms within a crystal

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5
Q

Capillary action

A

flow of liquid within a porous material due to the attraction of the liquid molecules to the surface of the material and to other liquid molecules

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6
Q

Clausius-clapeyron equation

A

Mathematical relationship between the temperature, vapor pressure, and enthalpy of vaporization for a substance

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7
Q

Cohesive force

A

Force of attraction between identical molecules

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8
Q

Condensation

A

Change from a gaseous to a liquid state

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9
Q

Covalent Network solid

A

Solid whose particles are held together by covalent bonds

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10
Q

Critical point

A

Temperature and pressure above which a gas cannot be condensed into a liquid

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11
Q

Crystalline solid

A

Solid in which the particles are arranged in a definite repeating pattern

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12
Q

Deposition

A

Change from a gaseous state directly to a solid state

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13
Q

Diffraction

A

Redirection of electromagnetic radiation that occurs when it encounters a physical barrier of appropriate dimensions

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14
Q

Dipole dipole attraction

A

Intermolecular attraction between two permanent dipoles

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15
Q

Dispersion force

A

(aka: London dispersion force)

attraction between two rapidly fluctuating, temporary dipoles; significant only when particles are very close together

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16
Q

Freezing

A

Change from a liquid state to a solid state

17
Q

Freezing point

A

Temperature at which the solid and liquid phases of a substance are in equilibrium

18
Q

Hydrogen bonding

A

occurs when exceptionally strong dipoles attract; bonding that exists when hydrogen is bonded to one of the three most electronegative elements: N, O, or F

19
Q

Induced dipole

A

temporary dipole formed when the electrons of an atom or molecule are distorted by the instantaneous dipole of a neighboring atom or molecule

20
Q

Instantaneous dipole

A

Temporary dipole that occurs for a brief moment in time when the electrons of an atom or molecule are distributed asymmetrically

21
Q

Intermolecular force

A

Non-covalent attractive force between atoms, molecules, and/or ions

22
Q

Ionic solid

A

Solid composed of positive and negative ions held together by strong electrostatic attractions

23
Q

Isomorphous

A

Possessing the same crystalline structure

24
Q

Melting

A

Change from a solid state to a liquid state

25
Melting point
Temperature at which the solid and liquid phases of a substance are in equilibrium
26
Metallic solid
Solid composed of metal atoms
27
Molecular solid
Solid composed of neutral molecules held together by intermolecular forces of attraction
28
Normal boiling point
Temperature at which a liquids vapor pressure equals 1 atm (760 torr)
29
Phase diagram
Pressure-temperature graph summarizing conditions under which the phases of a substance can exist
30
Polarizability
Measure of the ability of a charge to distort a molecule's charge distribution (electron cloud)
31
Sublimation
Change from a solid state directly to gaseous state
32
Supercritical fluid
substance at a temperature and pressure higher than its critical point; exhibits properties intermediate between those of gaseous and liquid states
33
Surface tension
Energy required to increase the area, or length, of a liquid surface by a given amount
34
Triple point
Temperature and pressure at which the vapor, liquid, and solid phases of a substance are in equilibrium
35
Van der Waals Force
attractive or repulsive force between molecules, including dipole dipole, dipole induced dipole, and London dispersion forces; does not include forces due to covalent or ionic bonding, or the attraction between ions and molecules
36
Vapor pressure
(aka: equilibrium vapor pressure) | pressure exerted by a vapor in equilibrium with a solid or a liquid at a given temperature
37
Vaporization
Change from liquid state to a gaseous state
38
Viscosity
Measure of a liquid's resistance to flow
39
X-ray crystallography
experimental technique for determining distances between atoms in a crystal by measuring the angles at which x-rays are diffracted when passing through the crystal