Chapter 10 Flashcards

1
Q

Molecules in a gas have complete freedom of motion.
KE overcomes the attractive forces between molecules.

A
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2
Q

Molecules in a liquid have limited freedom of motion.
Have enough KE to overcome some of the forces.

A
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3
Q

Molecules in a solid have no freedom of motion.
Though they vibrate, they can’t overcome the forces.

A
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4
Q

How strong are gas IM forces?

A

Weak

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5
Q

How strong are liquid IM forces?

A

Moderate

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6
Q

How strong are solid IM forces?

A

Strong

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7
Q

One state of matter can be transformed into another
by changing the

A

temperature, pressure, or both.

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8
Q

When you change the temperature, you change the
kinetic energy of the particles

A
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9
Q

− When you change the pressure, you change the
strength of the attractions between the particles

A
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10
Q

Covalent bonds are held together by _________
forces. Are these strong or weak?

A

intramolecular, Strong

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11
Q

Intermolecular attractions exist

A

between molecules

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12
Q

Where do intermolecular attractions happen in molecules?

A

+ ion/end of polar molecule to - ion/end of polar molecule

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13
Q

Are inter or intra molecular forces stronger? Why?

A

Usually intra, greater distance=less force to break attractions

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14
Q

What determines Physical properties? EG boiling/melting points, vapor pressure, viscosity

A

Intermolecular forces

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15
Q

Stronger Intermolecular forces can be correlated to

A

Higher melting/boiling point

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16
Q

What are intermolecular forces also known as?

A

Van der Waals forces

17
Q

What are the 3 types of attractions between neutral molecules?

A

Dipole-dipole, Hydrogen bonding, London Dispersion

18
Q

What type of bonding involves ions?

A

Ion-dipole force

19
Q

Can nonpolar atoms have dipole-dipole attraction? Can nonpolar gases be liquefied?

A

No, Yes

20
Q

Who proposed London Dispersion forces?

A

Fritz London

21
Q

How do London Dispersion forces happen? How does this affect other atoms?

A

E- can end up on the same side of atom (normally try to repel each other), creating temporary polarity, which influences its neighbors. + wants to bind to -

22
Q

What are London Dispersion forces? Where are they found?

A

Attractions between an instantaneous
dipole and an induced dipole. All molecules, regardless of their polarity

23
Q

What is the trend of molecular weight and dispersion forces?

A

As MW increases, dispersion forces increase.

24
Q

Do long or short molecules have stronger London forces? Why

A

Longer, more surface area so they have more interactions

25
Q

What molecules have dipole dipole forces? Why?

A

All polar molecules, because they have permanent dipole moments

26
Q

What is a dipole?

A

A molecule with charged ends

27
Q

What is a dipole dipole force?

A

Dipoles interacting via opposite end attraction

28
Q

18 onward(Just highlighted stuff)

A
29
Q

What is hydrogen bonding?

A

A type of dipole dipole force where H (H bond donor) is directly bonded to N, O, or F (H bond acceptor). This interacts with a lone pair of e- on an N, O, or F atom in another molecule.

30
Q

What are ion dipole forces?

A

Solvent pulling the ions from an ionic substance from the crystal, solvating them

31
Q

What does an anion dipole look like?

A
32
Q

What does a cation dipole look like?

A
33
Q

Ammonia and hydrogen fluoride both have unusually high boiling points due to _____

A

hydrogen bonding, because it causes have strong Intermolecular forces (which correlate to high boiling points)

34
Q

Is hydrogen bonding inter or intra molecular?

A

Inter

35
Q

What is Hydrogen bonding?

A

Strong intermolecular forces that happen between molecules with a very strong permanent dipole moment.

36
Q

What are ion dipole forces, and how are they formed?

A

When an ionic substance dissolves in H2O, the solvent pulls ions and solvates (surrounds) them. Solvent has +/- charged ends, which are attracted to the ions.

37
Q
A