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orga > Chap 1: substitution radicalaire > Flashcards

Chap 1: substitution radicalaire Flashcards

1
Q

4 possibilité de produire des radicaux

A
  1. thermolyse
  2. photolyse
  3. procédé redox
  4. mechanische energie/ultaschall
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2
Q

réaction en chaine

exemple de l’autooxydation du THF

A
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3
Q

sulfochloration du dodecane et saponification du dodecane sulfonyl chloride

A
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4
Q

Toluène + BR2+hy

Toluène + CL2 +hv

Toluène + I2 +hv

Toluène + SO2Cl2 +hv

A
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5
Q

Cl2+alcane

proportion primaire,secondaire, tertiaire

A
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6
Q

nbs+ Cyclohexène+dbpo

A
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7
Q

réactivité radicaux

CL CH3 I OH BR F

alcane,alcène…

A

I

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8
Q

AIBN

A
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9
Q

synthese de Williamson

A
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10
Q

agent de chloration

A
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11
Q

NBS+1-Butène initié par du peroxyde de dibenzoyle

A
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12
Q

autooxydation:

aldehydes+oxygène catalysé par acide

A
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13
Q
A
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orga (14 decks)

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