Chap 1 Flashcards
Fire Dyamics
__ __ describes the meeting point between fire science, materials science, fluid dynamics of gases, and heat transfer
Fire dynamics
All fires involve a heat producing chemical reaction between some type of __ and an __, most commonly __ in the air
Fuel
Oxidizer
Oxygen
Calcium hypochlorite, chlorine, ammonium nitrate, hydrogen peroxide, and methyl ethyl ketone peroxides are all..
Common oxidizers
A chemical process of oxidation that occurs at a rate fast enough to produce heat and usually light in the form of a glow or a flame
Combustion
A rapid oxidation process, which is a gas phase chemical reaction resulting in the evolution of light and heat
Fire
Form of energy associated with the motion of atoms or molecules in solids or liquids that is transferred from one body to another as a result of a temp difference between the bodies
Heat
Measure of a avg kinetic energy of the particles in a sample of matter, expressed in terms of units or degrees designated on a standard scale
Temperature
Physical science is the study of __ and __ and includes chemistry and physics
Matter
Energy
__ change occurs when a substance remains chemically the same but changes in size, shape, or appearance (water freezing (liquid to solid) and boiling (liquid to gas))
Physical
A __ __ occurs when a substance changes for one type of matter into another, such as two or more substances combining to form compounds
Chemical reaction
A material that will maintain combustion under specified environmental conditions
Fuel
Any material that readily yields oxygen or other oxidizing gas, or that readily reacts to promote or initiate combustion of combustible materials
Oxidizer
Anything that occupies space and has mass
Matter
Capacity to perform work; occurs when a force is applied to an object over a distance, or when a substance undergoes a chemical, biological, or physical transformation
Energy
Chemical process that occurs when a substance combines with an oxidizer
Oxidation
The rate at which fuel releases energy over time depends on many variables including:
Chemical composition
Arrangement
Density of fuel
Available oxygen for combustion
A fuels __ energy is the result of virbrations in molecules
Kinetic
Stored energy possessed buy and object that can be released in the future to perform work once released
Potential energy
Total amount of thermal energy (heat) that could be generated by the combustion (oxidation) reaction if a fuel were completely burned.
Heat of combustion
The heat of combustion is typically measured in..
Kj/g or MJ/kg
Energy possessed by a moving object because of its motion
Kinetic energy
Kinetic energy associated with the random motions of the molecules of a material or object; often used interchangeably with the terms heat and heat energy
Thermal energy
Types of energy:
Chemical
Thermal
Mechanical
Electrical
Light
Nuclear
Sound
Energy is measured in __ in the International System of Units (SI)
Joules (J)
The quantity of heat required to change the temp of 1 gram of water by 1 degree Celsius is..
4.2 joules
In the customary system, the unit of measurement for heat is the..
British thermal unit (Btu)
The amount of heat required to raise 1 pound of water 1 degree Fahrenheit is..
Btu
1055 J is equal to..
1 Btu
1 calorie is equal to..
4.19 J
Reactions that emit energy
Exothermic reactions
Reactions that absorb energy
Endothermic reactions
Unit of work or energy in the International System of Units (SI); the energy (or work) when a unit force (1 newton) moves a body through a unit distance (1 meter)
Joule ( J )
Chemical reaction between two or more materials that changes the materials and produces heat
Exothermic reaction
Chemical reaction in which a substance absorbs heat
Endothermic reaction
Chemical decomposition of a solid material by heating. Precedes combustion of a solid fuel
Pyrolysis
Physical process that changes a liquid into a gaseous state; the rate depends on the substance involved, heat, pressure, and exposed surface area
Vaporization
Moment when a mixture of fuel and oxygen encounters an external heat source with sufficient heat or thermal energy to start the combustion reaction
Piloted ignition
Initiation of combustion by heat but without spark or flame
Autoignition
The lowest temp at which a combustible material ignites in air without spark or flame
Auto ignition Temp (AIT)
The auto ignition temp of a substance is always __ than its piloted temp
Higher
Two modes of combustion
Flaming
Nonflaming
__ __ occurs more slowly and at a lower temp producing a smoldering glow in the materials surface
Nonflaming combustion
__ __ is commonly referred to as fire. Produces a visible flame above the materials surface
Flaming combustion
To draw in and transport solid particles or gases by the flow of a fluid
Entrain
Materials produced and released during burning
Products of combustion
Result of inefficient combustion of a fuel; the less efficient the combustion, the more products of combustion are produced rather than burned during the combustion process
Incomplete combustion
Fuels in which the energy of combustion derives principally from carbon
Carbon-based fuels
Petroleum based organic compound that contains only hydrogen and carbon; may also be used to describe those materials in a fuel load which were created using hydrocarbons such as plastics or synthetic fabrics
Hydrocarbon fuel
Heat and smoked are described as..
Products of combustion
Smoke is an aerosol comprised of gases, vapor, and..
Solid particulates
Smoke is a byproduct of..
Incomplete combustion
Examples of left over fuel from incomplete combustion..
Smoke and ash
Unburned fuel is smoke, and it has the potential to..
Burn
When the air supply is __, the level of incomplete combustion is __, which produces more smoke
Limited
Higher
__ is composed of a wide range of toxic and flammable gases and particulates
Smoke
Fatal condition caused by severe oxygen deficiency and an excess of carbon monoxide and/or other gases in the blood
Asphyxiation
Colorless, toxic, and flammable liquid until it reaches 79 degrees F. Above that it becomes a gas with a faint odor similar to bitter almonds
Hydrogen Cyanide (HCN)
Acts as a chemical asphyxiant. It’s molecules attach to hemoglobin, decreasing the bloods ability to carry oxygen
CO
CO combines with hemoglobin about __ times more effectively than oxygen
200
HCN is __ times more toxic than CO
35
HCN prevents the body from using __ at the cellular level
Oxygen
Colorless, odorless, heavier than air gas that neither supports combustion nor burns
CO2
Force per unit area exerted by a liquid or gas measured in psi or kPa
Pressure
The tendency or capacity of a liquid or gas to remain afloat or rise
Buoyant
Total amount of heat released per unit time. Typically measured in kW or MW
HRR
The measure of the rate of heat transfer to or from a surface. Typically expressed in kW/m2
Heat flux
Result of Exothermic reactions, occurring spontaneously in some materials under certain conditions, where heat is generated at a rate sufficient to raise the temp of the material
Self-Heating
Initiation of combustion of a material by an internal chemical or biological reaction that has produced sufficient heat to ignite the material
Spontaneous ignition
Gases always move from areas of __ pressure to __ pressure
Higher
Lower
__ is the thermal kinetic energy needed to release the potential chemical energy in a fuel
Heat
Temperature is the measurement of the avg __ __ in the particles of a sample of matter
Kinetic energy
__ energy is the most common source of heat in combustion reactions
Chemical
The oxidation process almost always results in the production of __ energy. The energy dissipates almost as quickly as it is generated.
Thermal
Friction or compression generates __ energy
Mechanical
__ is generated when a gas is compressed
Heat
The transfer of heat from one point or object to another is part of the study of __
Thermodynamics
Thermal equilibrium is where all areas of an object are a uniform..
Temperature
The rate at which heat transfers is related to the temperature differential of the bodies and the __ __ of the materials involved
Thermal conductivity
__ is the transfer of heat through and between solids
Conductivity
Heat transfer due to conduction is dependent upon 3 factors:
-Area being heated
-Temp difference between heat source and the material being heated
-Thermal conductivity of the heated material
Insulating materials slow the __ of heat from one solid to another
Conduction
__ is the transfer of thermal energy by the circulation or movement of a fluid (fluid or gas)
Convection
The point at which 2 regions that are in thermal contact no longer transfer heat between them because they have reached the same temp
Thermal equilibrium
The propensity of a material to conduct heat within its volume
Thermal conductivity
Physical flow or transfer of heat energy from one body to another, through direct contact or an intervening medium, from the point where the heat is produced to another location, or from a region of high temp to a region of low temp
Conduction
Transfer of heat by the movement of heated fluids or gases, usually in an upward direction
Convection
Transmission or transfer of heat energy from one body to another body at a lower temp through intervening space by electromagnetic waves
Radiation
Radiated heat energy travels in a straight line at the __ __ __
Speed of light
Radiation is a common cause of..
Exposure fires
A fire ignited in fuel packages or bldgs that are remote from the initial fuel package or bldg of origin
Exposure fire
Fuel that is being oxidized or or burned during combustion
Reducing agent
Amount of energy delivered over a given period of time. And the rate at which energy transfers.
Power
The SI unit of power or rate of work equal to 1 joule per second (J/s)
Watt (W)
A multiple of thousands
Kilo
A multiple of millions
Mega
__ describes the density of gases in relation to air.
Vapor density
Air has a vapor density of..
1
The vapor density of gas provides an indication of where a gas will __ at an incident
Collect
__ __ is the ratio of the mass of a given volume of a liquid compared to the mass of an equal volume of water at the same temp.
Specific gravity
Water is assigned a specific gravity of..
1
The specific gravity of a liquid indicates whether the liquid will __ on the surface of water or __
Float
Sink
__ __ is the min temp at which a liquid gives off sufficient vapors to ignite, but not sustain combustion, in the presence of a piloted ignition source
Flash point
__ __ is the temp at which a piloted ignition of sufficient vapors will begin a sustained combustion reaction
Fire point
Flammable liquids called polar solvents such as alcohols (methanol, ethanol) will readily..
Mix with water
Materials that are __ in water will mix in any proportion
Miscible
Pyrolysis of wood begins at temps below __
400*F
The energy release in fire is directly proportional to the amount of __ available for combusiton
Oxygen
At normal ambient temps (68*F), materials can ignite and burn in oxygen concentrations as low as __
15%
Range between the upper and lower flammable limits in which a substance can ignite
Flammable (explosive) range
As flaming combustion occurs, the molecules of a fuel gas and oxygen break apart to form..
Free radicals
Electrically charged, highly reactive parts of molecules released during combustion
Free radicals
Extinguishment of a fire by interruption of the chemical chain reaction. (Dry chemical, Halon, etc)
Chemical flame inhibition
Compartment fire development depends on whether the fire is __ __ or __ __
Fuel limited
Vent limited
All compartment fires begin in the incipient stage as __ __ fires
Fuel limited
4 stages of fire development
Incipient
Growth
Fully developed
Decay
Description of a fire burning in the open with no restrictions to its oxygen supply
Open burning (free burning)
Transition from the incipient to the growth stage can occur in a matter of __ depending on the type and configuration of __
Seconds
Fuel
Horizontal movement of a layer of hot gases and combustion by-products from the center point of the plume
Ceiling jet
The drawing in and transporting of solid particles or gases by the flow of liquid
Entrainment
A fire the enters vent limited decay __ __ indicate that the fire is in its final stage of development
Does not
The __ of a fire in a compartment influences the entrainment of air into the fire
Location
Area surrounding a heat source in which there is sufficient air available to feed a fire
Combustion zone
__ __ is the tendency of gases to form into layers according to temp, gas density, and pressure
Thermal layering
Changes in ventilation and flow path can significantly alter..
Thermal layering
__ or __ flames may move through the hot gas layer
Isolated
Intermittent
The appearance of isolated flames is sometimes an immediate indicator of ..
Flashover
The interface between the hot gas layers and cooler layer of air is commonly referred to as the __ __ because the net pressure is zero, or __ where the layers meet
Neutral plane
Neutral
Even if temps decrease, __ can continue where a large volume of flammable products of combustion can accumulate within the compartment. These gases are fuel that can ignite with new oxygen source.
Pyrolysis
Warning: even coordinated tactical vent increases the combustion rate in __ __ fire
Vent limited
Rapid transition from growth to fully developed stage
Flashover
Rapid fire development has been responsible for numerous ff..
Deaths and injuries
Instantaneous explosion or rapid burning of superheated gases that occurs when oxygen is introduced into an oxygen depleted confined space
Backdraft
Flashover typically occurs during the fires __ stage
Growth
As flashover occurs, the gas temps in the room reach __ or higher
1100*F
4 common elements of flashover:
-Transition in fire development-growth to fully developed
-Rapidity-flashover happens rapidly, in a matter of seconds
-Compartment-must be an enclosed space
-Pyrolysis of all exposed surfaces
The auto ignition temp of CO, the most abundant fuel gas created by most fires, is approx..
1100*F
When a fire is in __ __ decay, the intro of new oxygen can trigger flashover quickly
Vent limited
The available __ limits the peak heat release in a fuel limited, fully developed fire
Fuel
Warning: additional ventilation will cause an already __ fire to grow
Ventilated
It is not possible to make enough __ in a compartment to transition a fire from vent limited to fuel limited conditions
Openings
__ __ occurs when a structural member fails-usually because of exposure to heat- and introduces a new source of oxygen to the fire
Unplanned ventilation
Unplanned ventilation is often the result of:
Occupant action
Fire effects on bldg
Actions other than planned, systematic, and coordinated tactical ventilation
Warning: wind speeds as low as __ mph can create wind driven fire conditions
10
Caution: a __ __ can overpower the natural convective effect of a fire and drive the smoke and hot gases back into the bldg
Strong wind
FF’s can influence fire dynamics in a number of ways:
Temp reduction
Fuel removal
Oxygen exclusion/flow path control
Chemical flame inhibition
Form of gas ignition; the ignition of accumulated flammable products of combustion and air that are within their flammable range
Smoke explosion
The total quantity of combustible contents of a bldg, space, or fire area, including finish and trim
Fuel load
The orientation of fuels as well as their surface-to-mass ratio will also influence the __ and __ of fire spread
Rate
Intensity
__ __ coverings may add carbon fuel (wooden siding) or petroleum fuels (vinyl siding) to the fuel load
Exterior wall
Thermal properties of a bldg include:
Insulation
Heat reflectivity
Retention
Unprotected engineered steel and wooden trusses can fail after __ to __ minutes of exposure to fire
5
10
For steel trusses, __ is the critical temp of steel- the temp at which steel begins to weaken
1000*F
Warning: entire pieces of decking may fall into the fire when __ __ fail. There may be no indications from the exterior that the trusses no longer support the roof decking.
Lightweight trusses
The bowstring truss’ compressional forces within the top chord act to force the load bearing walls __ as well as __
Outward
Downward
Web members in the bowstring truss transfer __ from the bottom chord and __ from the top chord onto load bearing walls
Tension
Compression