Ch.4 Atomic Structure Flashcards

1
Q

what does atomos mean?

A

something that cannot be cut

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2
Q

what are the 5 main points of John Dalton’s Atomic Theory

A
  • matter is made of tiny, indivisible particles called atoms
  • atoms of the same element are identical in shape, size and weight
  • atoms of different elements are distinguished by different weights
  • atoms of different elements combine in fixed, simple ratios to form compounds
  • atoms cannot be destroyed or created, only re-arranged (law of conservation of energy as well)
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3
Q

Why do chemical reactions occur

A

chemical reactions occur due to the arrangement of the reacting atoms

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4
Q

what are isotopes?

A

atoms of the same element can have different weights and are called isotopes (no. of neutrons vary)

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5
Q

what are the 6 main points of Modern Atomic Theory

A
  • an element is made up of atoms
  • atoms are made up of protons, neutrons and electrons (are divisible)
  • all atoms of an element have the same number of protons and electrons but may have a different number of neutrons (isotopes)
  • atoms of different elements have a different no. of protons leading to a difference in chemical properties of said element
  • atoms of different elements combine in whole numbers to form compounds
  • atoms cannot be destroyed or created or changes in an ordinary chemical reaction, they are only re-arranged
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6
Q

what are orbits or shells

A

electrons revolve around the nucleus at very high speeds in paths called orbits or shells

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7
Q

what is an electron

A

sub-atomic particle that has a negative electric charge (known as a point charge)

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8
Q

what is a proton

A

positively charged subatomic particle

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9
Q

what is a neutron

A

subatomic particle that has no charge

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10
Q

what kind of force is present between protons and electrons

A

electrostatic force (like charges repel, unlike charges attract)

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11
Q

why do electrons not fall into the nucleus?

A

electrons move very fast around the nucleus
this high - speed movement prevents them from falling into the nucleus (constant motion)

(this high speed movement balances the electrostatic force of attraction between protons and electrons

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12
Q

what is an electronic configuration?

A

distribution of electrons in the shells of an atom

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13
Q

what is a molecule?

A

an electrically neutral group of two or more atoms held together by chemical bonds, formed either by gaining, loosing or sharing of electrons

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14
Q

atomicity

A

number of atoms in a molecule of an element

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15
Q

what are the classifications of elements based on atomicity

A

Monoatomic (He, Al)
Diatomic (H2, O2, N2)
Polyatomic (S8, P4)

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16
Q

What is a chemical formula?

A

an expression which states the number and type of atoms present in one molecule of the compound using symbols and subscripts

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17
Q

valency

A

the combining capacity of an atom of an element or the number of hydrogen atoms with which it combines or replaces

otherwise,

Valency is the number of electrons gained/lost/shared as an atom tried to attain the electronic configuration of the nearest noble gas

18
Q

What is the octet rule?

A

it states that the outermost shell of an atom cannot accommodate more than 8 electrons, even if it has the capacity to hold more

19
Q

what is the valence shell

A

outermost shell/orbit of an atom

20
Q

what are valence electrons

A

electrons present in the valence shell

21
Q

what are the different classifications based on valency of elements

A

Monovalent - Chlorine (Hydrogen Chloride)
Divalent - Oxygen (Water)
Trivalent - Aluminium
Tetravalent - Silicon
Pentavalent - Phosphorous

22
Q

what is the valency of noble gases?

A

0 (no need to share, lose, or give electrons; they have completed duplets/octets)

23
Q

valency of hydrogen

A

1

24
Q

On what basis does an atom give/take electrons

A

whichever process takes the least energy

25
Q

Ions

A

charged particles that are formed when an atom or group of atoms gains or loses an electrons

eg. hydrogen becomes hydrogen ion/proton when it gives its electron (aka H+)

26
Q

cation

A

a positively charged ion

eg. Sodium (Na+ + e-), Aluminium, Calcium

27
Q

Electropositivity

A

the ability of elements to donate electrons to form positive ions

eg. metals

28
Q

how is valency for elements with 5/6/7 valence electrons calculated

A

8 - no. of valence electrons

29
Q

anion

A

a negatively charged ion

eg. Chlorine (Cl + e- = Cl-), Oxygen becoming oxide ion

30
Q

Electronegativity

A

ability of an element to receive electrons and form negative ions (anions)

31
Q

what suffix is added to the name of an anion

A

‘ide’

eg. Chloride, Oxide, Sulphide

32
Q

why do transition metals have variable valency

A

they can donate electrons from the penultimate (second outermost) shell

hence they show more than 1 valency

33
Q

how do you differentiate between ions of elements with variable valency

A

suffix ‘ous’ is added to one with lower valency
suffix ‘ic’ is added to one with higher valency

eg. Fe2+ is ferrous and Fe3+ is ferric

34
Q

what non metals also show variable valency

A

Phosphorus - 3,5 (aka Phosphorus Trichloride and Phosphorus Pentachloride)

Sulfur - 2,4,6

*these elements have empty subshells

35
Q

Polyatomic Ions

A

group of atoms that functions as a single unit in a chemical reaction and carries a charge is called polyatomic ion

36
Q

what are polyatomic ions also called

A

Radicals

37
Q

What happens when suffix ‘ate’ is changed to ‘ite’

A

oxygen atom decreases

eg. Nitrate ion is NO-3 and Nitrite NO-2

38
Q

what happens when prefix ‘per’ is added to ‘ate’

A

oxygen is increased by one

eg. Chlorate is CL3-2 and Perchlorate is CLO4-

39
Q

what happens when ‘bi’ suffix is added

A

hydrogen atom is added

eg. Carbonate ion is CO3-2 and Bicarbonate ion is HCO3

40
Q

👩🏽‍🔬🧪📚👩🏽‍🎓 chemistry genius?

A

YESS MAAM <3