Ch3: Quantum phenomena Flashcards
Define photoelectric effect
Electrons are emitted from a metal surface when electromagnetic radiation above the threshold frequency is directed at the metal.
Define threshold frequency
The minimum value for incident radiation for the photoelectric effect to happen.
Define work function
Minimum energy needed to escape surface of the metal.
Ekmax=?
hf - work function
Threshold frequency fmin=?
fmin= work function / h
Define stopping voltage
The minimum energy needed to stop photoelectric emission
In a vacuum photocell electrons are emitted at the ….. and attracted to the …..
Photocathode, anode
Does intensity affect ekmax?
No, still one electron absorbing one photon
Incident intensity is proportion to…
Photoelectric current
Define ionisation
Process of creating ions
How can you calculate the ionisation energy of a gas atom?
In a low pressure gas tube, increase pd between filament and anode, when current increases is the ionisation energy of the gas atoms, which = eV where e is charge of electron.
Define excitation
Atoms can absorb energy from colliding electrons without being ionised.
How can you calculate excitation energies of a gas?
Increase pd between filament and anode, measure pd when the anode current falls.
What is an electron volt?
unit of energy equal to work done when an electron is moved through a pd of 1V
An electron in a shell ….. to the nucleus has less energy.
Closer
Define ground state
The lowest energy state of an atom.
What conditions have to be met for photon absorption to cause excitation?
The energy of the photon is exactly equal to the gain in the electrons energy, or the difference in initial and final energy levels.
Why are excited atoms unstable?
An electron that moves to an outer shell leaves a vacancy
What is deexcitation?
Vacancy filled by outer shell electron transferring to inner shell, a photon is emitted by the electron and the atom moves to a lower energy state.
energy of emitted photon hf=
E1 - E2
E1-higher energy state.
E2- lower energy state
Describe how a fluorescent tube works
Glass tube with fluorescent coating with mercury vapour. Mercury atoms ionise and excite as they collide. Mercury atoms deexcite and emit UV photons, visible light, low energy photons. UV photons absorbed by coating, exciting atoms. Coating atoms deexcite in stages, releasing visible photons.
Define a line spectrum
Spectrum of discrete lines of different colours, each of which corresponds to a certain wavelength. Each line spectrum specific to the element. Photons from one line have the same energies. Photon emitted due to deexcitation of atom.
Which two equations could you use to calculate the energy of a photon?
hf= E1-E2
f=c / wavelength
Wave nature of light: …..
Particle nature of light: ……..
Electron diffraction
Photoelectric effect