Ch3: Quantum phenomena Flashcards

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1
Q

Define photoelectric effect

A

Electrons are emitted from a metal surface when electromagnetic radiation above the threshold frequency is directed at the metal.

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2
Q

Define threshold frequency

A

The minimum value for incident radiation for the photoelectric effect to happen.

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3
Q

Define work function

A

Minimum energy needed to escape surface of the metal.

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4
Q

Ekmax=?

A

hf - work function

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5
Q

Threshold frequency fmin=?

A

fmin= work function / h

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6
Q

Define stopping voltage

A

The minimum energy needed to stop photoelectric emission

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7
Q

In a vacuum photocell electrons are emitted at the ….. and attracted to the …..

A

Photocathode, anode

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8
Q

Does intensity affect ekmax?

A

No, still one electron absorbing one photon

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9
Q

Incident intensity is proportion to…

A

Photoelectric current

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10
Q

Define ionisation

A

Process of creating ions

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11
Q

How can you calculate the ionisation energy of a gas atom?

A

In a low pressure gas tube, increase pd between filament and anode, when current increases is the ionisation energy of the gas atoms, which = eV where e is charge of electron.

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12
Q

Define excitation

A

Atoms can absorb energy from colliding electrons without being ionised.

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13
Q

How can you calculate excitation energies of a gas?

A

Increase pd between filament and anode, measure pd when the anode current falls.

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14
Q

What is an electron volt?

A

unit of energy equal to work done when an electron is moved through a pd of 1V

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15
Q

An electron in a shell ….. to the nucleus has less energy.

A

Closer

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16
Q

Define ground state

A

The lowest energy state of an atom.

17
Q

What conditions have to be met for photon absorption to cause excitation?

A

The energy of the photon is exactly equal to the gain in the electrons energy, or the difference in initial and final energy levels.

18
Q

Why are excited atoms unstable?

A

An electron that moves to an outer shell leaves a vacancy

19
Q

What is deexcitation?

A

Vacancy filled by outer shell electron transferring to inner shell, a photon is emitted by the electron and the atom moves to a lower energy state.

20
Q

energy of emitted photon hf=

A

E1 - E2
E1-higher energy state.
E2- lower energy state

21
Q

Describe how a fluorescent tube works

A

Glass tube with fluorescent coating with mercury vapour. Mercury atoms ionise and excite as they collide. Mercury atoms deexcite and emit UV photons, visible light, low energy photons. UV photons absorbed by coating, exciting atoms. Coating atoms deexcite in stages, releasing visible photons.

22
Q

Define a line spectrum

A

Spectrum of discrete lines of different colours, each of which corresponds to a certain wavelength. Each line spectrum specific to the element. Photons from one line have the same energies. Photon emitted due to deexcitation of atom.

23
Q

Which two equations could you use to calculate the energy of a photon?

A

hf= E1-E2
f=c / wavelength

24
Q

Wave nature of light: …..
Particle nature of light: ……..

A

Electron diffraction

Photoelectric effect

25
Q

State the de Broglie hypothesis

A

Matter waves have dual wave particle nature

26
Q

De Broglie equation

A

wavelength = h / mv

27
Q

Evidence of the de Broglie wavelength?

A

Electrons diffract into rings when passed through thin metal foil, and diffract less when the speed increases which makes the de Broglie wavelength smaller.