Ch. 5, 36, 32 Flashcards
polymers
materials made of large, long molecules formed by chemically reacting molecular building blocks called monomers; common polymers or plastics include polyethylene, Plexiglas
polymerization
links monomers together to produce polymer
thermoplastic
can be heated and molded to shaped after polymerization reaction
thermoset polymers
polymers with a cross-linked rather than a linear structure tend not to melt, rather they decompose, can’t be heated or molded, tend to be stronger, most dental resins are cross-linked and are therefore thermoset
free radicals
the polymerization reaction of acrylic resins is called free radical or addition polymerization; a free radial or unpaired electron is involved in reaction and one monomer is added at a time to polymer chain as reaction proceeds
initiation
first step in addition polymerization; first formation of free radicals then the free radical reacts with a monomer molecule to start a growing chain
propagation
second step in addition polymerization, which is the growth or lengthening of the chain; involves adding the 2nd, 3rd, 4th, and later monomers to the growing chain until that chain is hundreds/thousands of monomers long
termination
two free radicals at the ends of two growing chains may react; if they do, they will form a carbon-carbon bond; at this point, no free radicals are left to continue growth of the chain
heat activated acrylic resins
typically use benzoyl peroxide as the initiator, heat is the activator, in hot water bath; most complete and partial dentures use heat-activated acrylic resins for denture base
chemically activated
use BPO as initiator, tertiary amines as activator; used to make temp crows, ortho retainers
light activated
use several activator and initiator chemicals; the activator absorbs light and then reacts with the initiator; supplied as single paste
dual-cure
have both chemical and light-activated capabilities
working time
can occur very rapidly, an inhibitor, typically hydroquinone reacts with the first free radicals that are produced during the initiation process, this reaction competes with polymerization process and wins
percolation
repeated expansion and contraction can open and close gaps at the margin of a restoration, can result in leakage and recurrent caries
macrofilled composite
first type of dental composite, large size of filler particles in macrofilled composites results in a restoration that feels rough to explorer and can appear rough to the eye