ch. 4 - arrangement of electrons in atoms Flashcards
Rutherford’s model of the atom…
didn’t describe how electrons took up the space surrounding the nucleus
speed of light
3.0 x 10^8
plank’s constant
6.626 x 10^-34
Bohr’s atomic model…
explains the emission spectra of hydrogen atoms, and proposed that electrons occupy specific energy levels
de Broglie…
suggested that electrons could be considered as waves confided to the space around an atomic nucleus; electrons can be bent or diffracted, and can interfere with one another, like waves
Heisenberg Uncertainty Principle
it is impossible to determine simultaneously both the position and velocity of an electron (or any other particle)
principal quantum number (n)
indicates the main energy level occupied by the electron
angular momentum quantum number (l)
(n-1) indicates the shape of the orbital
magnetic quantum number (m sub l)
(-1, 0, +1) indicates the orientation of an orbital around the nucleus
spin quantum number (m sub s)
(+1/2, -1/2) fundamental spin states of an electron in an orbital
Aufbau principle
electrons fill lower energy levels first before occupying higher energy levels
Pauli exclusion principal
no two electrons in the same atom can have the same set of four quantum numbers
Hund’s rule
orbitals of equal energy must be occupied by one electron before a second
all electrons in singly occupied orbitals must have the same spin state