Ch 20/21 Flashcards
What reagents do you use for the following reaction?
H2O
H2SO4 (catalyst)
What reagents do you use for the following reaction?
H20
HCl (Catalyst)
What reagents do you use for the following reaction?
H2NCH2CH3
2 equivalent
What reagents do you use for the following reaction?
CH3OH
CH3ONa
What reagents do you use for the following reaction?
MCPBA
HOSO2CF3
What is the product of the following reaction?
What is the product of the following reaction?
Put the following in order for Aptitude for Migration with MCPBA
most likely to migrate –> least likely to migrate
What reagents do you use for the following reaction?
PROTECTING AMINE (STEP 1)
BOC2O
NaHCO2
DEPROTECTING AMINE (STEP 2)
TFA
CF3COH2
What reagents do you use for the following reaction?
H2N-R’
DCC
What reagents do you use for the following reaction?
HO-R’
DCC
DMAP
What reagents do you use for the following reaction?
1) NaOCH3, HOCH3
2) CH3CO2H
What reagents do you use for the following reaction?
1) NaOH, H2O
2) CH3CO2H
What reagents do you use for the following reaction?
1) NaOCH2CH3
2) CH3CO2H
When do you use BOC protecting group?
Why?
To protect an amine group from reacting - ensuring an OH group does react
amines are more basic and nucleophilic compared to alcohols