CH 18(CH 10 Kaplan) Acids and Bases Flashcards

1
Q

What is the definition or an Arrhenius Acid/Base?

A
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2
Q

What is the definition or an Arrhenius Acid/Base?

A
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3
Q

What is the definition of a Lewis Acid/Base?

A

Lewis Acid = Electron Acceptor, has a vacant orbital to accept a lone pair

Lewis Base= Electron Donor

Most comprehensive definition

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4
Q

Lower the pKa the (stronger/weaker the acid)?

A

Lower the pKa the stronger the acid

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5
Q

Higher the pKa the (stronger/weaker the acid)?

A

Higher the pKA = weaker acid

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6
Q

Higher Ka = stronger or weaker acid?

A

Higher Ka = stronger acid

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7
Q

Lower Ka = stronger or weaker acid?

A

Lower Ka = weaker acid

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8
Q
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9
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10
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11
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12
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13
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14
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15
Q
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16
Q

What is the definition of a Bronsted-Lowry Acid?

A
17
Q

What is the definition of a Bronsted-Lowry Base?

A
18
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19
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20
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21
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22
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23
Q

What is the definition of a Lewis Acid?

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24
Q

What is a Lewis Base?

A
25
Q

What is the definition of a Lewis Acid-Base reaction?

A

Donation and acceptance of a lone pair to form a covalent bond

26
Q
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27
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28
Q

Which species are considered amphoteric? (3 answers)

A

1) Partially dissociated conjugated base of polyvalent acid
2)Hydroxides of certain metals (Al, Zn, Pb, and Cr)
3)Oxidizing and reducing agents

29
Q

True or false: Every Arrhenius acid is a Bronsted-Lowry acid and every Bronsted-Lowry Acid is a Lewis Acid?

A

True

30
Q

Which acid/base definition is considered amphiprotic?

A

Bronsted-Lowry: can donate or accept a proton making it amphiprotic

31
Q
A
32
Q

/(Electronegative elements positioned near an acidic proton ________ (increase/decrease) acid strength by__________________

A

Electronegative elements positioned near an acidic proton INCREASE acid strength by pulling electron density away from the bond holding the proton

33
Q

What are the approximate pH values for these reactions?

A
34
Q

Periodic Table trends: Acidity _________ across a period and down a group

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35
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36
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37
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