ch 15-22 solvents and reagentws Flashcards

1
Q

HNO_3 / H2 SO4

A

Nitration - Adds No_2 to ring (meta director)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Br_2 / Fe Br_3 (or Cl)

A

Halogenation - Adds Halogen to Benzene Ring (OP director)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

SO_3 / H2SO4

A

Sulfonation - Adds SO3H to ring (meta director)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Cl - C = O - R / AlCl3

A

Acylation - Attatched C = O - R to a ring (meta director) ( can complete multiple cycles)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

R - Cl / AlCl3

A

Alkylation - Adds R group to ring (OP director) (doesn’t rearrange)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

NBS / Heat

A

Adds Br to C chain in ring (OP director)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

NaOH

A

Converts X group to alkene (Br -> =)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Fe / HCl

A

Converts NO2 to NH2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

H2SO4 / H2O

A

Removed SO3H

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

H2 / EtOH

A

Removes O from C = O to only have. carbon chain

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

mcpba

A

Transforms alkene to epoxide

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

H2 / Raney Ni

A

Transforms NO2 to NH2

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

KMnO4, NaOH, H2O

A

Adds carboxylic acid to C chain

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

HCl / H2O

A

Converts OH to Cl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

H2 Pd/C

A

Removes =O from C=O

How well did you know this?
1
Not at all
2
3
4
5
Perfectly