ch 15-22 solvents and reagentws Flashcards
HNO_3 / H2 SO4
Nitration - Adds No_2 to ring (meta director)
Br_2 / Fe Br_3 (or Cl)
Halogenation - Adds Halogen to Benzene Ring (OP director)
SO_3 / H2SO4
Sulfonation - Adds SO3H to ring (meta director)
Cl - C = O - R / AlCl3
Acylation - Attatched C = O - R to a ring (meta director) ( can complete multiple cycles)
R - Cl / AlCl3
Alkylation - Adds R group to ring (OP director) (doesn’t rearrange)
NBS / Heat
Adds Br to C chain in ring (OP director)
NaOH
Converts X group to alkene (Br -> =)
Fe / HCl
Converts NO2 to NH2
H2SO4 / H2O
Removed SO3H
H2 / EtOH
Removes O from C = O to only have. carbon chain
mcpba
Transforms alkene to epoxide
H2 / Raney Ni
Transforms NO2 to NH2
KMnO4, NaOH, H2O
Adds carboxylic acid to C chain
HCl / H2O
Converts OH to Cl
H2 Pd/C
Removes =O from C=O