Ceramics Flashcards
Porcelain
COMPOSITION
feldspar 60-80%, glass phase leucite
quartz 15-25%, stability
kaolin 0-5%, moldability
metaloxides Shade
Glass-based porcelains (silica-based)
– Feldspathic porcelains
– Reinforced feldspathic porcelains
•Metal oxide ceramics (High-strength)
Aluminum-oxide ceramic (alumina)
Zirconium-oxide ceramic (zirconia)
What does Sintering do?
making objects from powder, by heating the material in a sintering furnace below its melting point (solid state sintering) until its particles adhere to each other
Feldspathic porcelain uses
- Veneers
* Veneering porcelain fused to metal (PFM) crowns
Reinforced feldspathic porcelain can be reinforced with…
- Alumina reinforced feldspathic porcelain
- Leucite reinforced feldspathic porcelain
- Lithium reinforced feldspathic porcelain
Lithium disilicate crystals, flexural strength: 340 MPa - Fluorapatite reinforced feldspathic porcelain
Fluorapatite crystals, flexural stregth: 110 MPa
Al2O3 crystals, flexural strength: 131 MPa
Leucite crystals, flexural strength: 220 MPa
Aluminum-oxide ceramic (alumina), flexural strength:
200 MPa
– Zirconium-oxide ceramic – ZrO 3 (zirconia), flexural strength:
1000-1500 MPa
(yttria) added
Crystal forms of zirconia:
cubical (high temperature)
tetragonal (while cooling down) monoclinic (room temperature)
Non-silica-based ceramics Considerations
high-strength ceramics
– Special silane application (chemical bond to metal-oxides in ceramic and to cement)
– Resin based cement
Silica-based ceramics Considerations
glass-ceramics
– Etching with hydrofluoric acid (increases surface roughness for better micromechanical retention)
– Silane application (chemical bond to silica in ceramic and to cement)
– Resin based cement