Cements 3 Flashcards
1
Q
Uses of glass ionomer cements
A
- cavity base/lining
- luting
- filling
2
Q
GIC is a development of what?
A
- polycarboxylates
- change zinc oxide to glass particles
3
Q
How is GIC a lining/base?
A
- under amalgam or composite
- sandwich technique for composite
4
Q
Luting with GIC is used in which departments?
A
- prosthodontics
- orthodontics
5
Q
How is GIC used for fillings?
A
- use product specifically designed for restorative purposes
- ISO standards type I and II
- class V, III and I and I in deciduous teeth
6
Q
GIC are also called what?
A
polyalkenoates
7
Q
Composition of GIC
A
- hand mix or encapsulated
- powder is aluminosilicate glass made from aluminium oxide, silicon oxide and calcium fluoride
- liquid is aqueous solution of polyacid, originally acrylic acid but also maleic, itaconic or copolymers
- more recently polyvinyl phosphoric acid (much stronger)
- or anhydrous cements (powder containing freeze dried acid) and water
8
Q
GIC setting reaction
A
acid +base _> salt and water
- MO.SiO2 + H2A -> MA + SiO2 + H2O
9
Q
GIC setting is complex. Gove the 3 overlapping steps
A
- dissolution (acid and glass particles react)
- gelation (crosslinking due to calcium ions reacting with polyacid)
- hardening (crosslinking due to aluminium ions reacting with polyacid)
10
Q
Initial setting and maturation of GIC
A
- water exposure can effect setting - dilutes acid
- can lead to weak cement (chalky appearance)
- need to protect - varnishes sold by manufacturers
- dentine bonding agents often used - may leave a ledge (need to deal with it to prevent biofilm formation)
11
Q
What acid is often added to GICs?
Why?
A
- tartaric acid
- helps break down glass particle surface
- reacts with aluminium ions
- extends WT - only calcium ions reacting with glass
- once tartaric acid used up, aluminium ions reacts with glass
- GICs have better WTs and STs
12
Q
Structure of GIC
A
- final cement has a cored structure
- glass particles surrounded by polyacid matrix
13
Q
What properties are effected by porosity?
A
- method of mixing
- cement viscosity
14
Q
How does method of mixing influence porosity?
A
- hand mixing is difficult to accurately proportion components
- mechanical means it’s already proportioned by manufacturers
15
Q
Cement viscosity - how does that affect porosity?
A
- luting cements have lower viscosity
- restorative cements have higher