Cement Flashcards
Name 5 additions which can be used In combination with PC .
- Fly Ash (FA) –
- Ground Granulated Blastfurnace Slag (GGBS)
- Condensed Silica Fume (CSF)
- Metakaolin (MK)
- Limestone
How is fly ash (FA) produced?
- Coal, consisting of a mixture of carbonaceous matter and other minerals is pulverised to a fine material before being injected into the power station furnace.
- Combustion of coal produces fine ash which is precipitated from flue gases either mechanically or electrostatically.
- Particles fuse to form tiny glass spheres of complex silicates
- FA is collected and stored.
What does characteristics of FA depend on?
Coal composition
Combustion temperature
Precipitation method
How is GGBS produced?
- Iron ore, coke and limestone are added to the blast-furnace at a temperature of around 1500C.
- Iron ore is chemically reduced to form molten iron and a fusion of lime from limestone and siliceous and aluminous residues from iron ore and coke produces slag.
- Molten slag is periodically tapped off and rapidly quenched using sprayed water to produce a granular material similar in size to coarse sand.
- ‘Granulated’ slag is then dried and ground to a fine powder in conventional grinding mills to form GGBS.
characteristics of GGBS.
Chemical composition of raw materials,
Degree of grinding
How is Silica fume (CSF) produced
- High purity quartz and coal are fired in submerged-arc electric furnaces.
- The escaping gaseous silicon monoxide (SiO) oxidises and condensates in the form of extremely fine spherical particles of amorphous silica (SiO2).
- Coarser particles are removed from flue gases by cyclone and finer particles (CSF) collected by baghouse filters.
- CSF is stored in either powder form or more commonly slurry form.
Characteristics of silica fume:
Chemical composition of raw materials,
Efficiency of heat recovery of furnace
how is Metakolin (MK) produced?
- Large quantities of coarse kaolin discarded as they are not fine enough for china and paper production.
- The raw material kaolin is thermally activated and the most common constituent, kaolinite (Al2Si2O5(OH)4) is dehydroxilised at 700-800C.
- The resulting calcined kaolinite clay is a very fine powder which is highly pozzolanic - MK.
Characteristics of Metakolin:
Chemical composition of raw materials,
Temperature of thermal activation
Influence of FA/GGBS/CSF/MK on fresh concrete properties:
FA / GGBS reduce water demand,
CSF / MK increase water demand,
They improve cohesion of the mix
Influence of FA/GGBS/CSF/MK on hydrating concrete properties:
Rate of hydration,
Setting times,
Development of early strength,
Development of long-term strength,
In what ways can limestone beneficially effect concrete?
workability,
stability,
density
permeation properties