CC16 - fuels Flashcards

1
Q

what is a hydrocarbon

A

a compound of only hydrogen and carbon

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2
Q

what is crude oil

A

natural resource a complex mixture of hydrocarbons
an important source of fuel and feedstock for petrochemical industry

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3
Q

why is crude oil a finite resource

A

takes so long to make it is being used faster than made and will one day run out

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4
Q

where does crude oil come from

A

formed underground at high temp and pressure over millions of years from plant and animal remains

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5
Q

what is crude oil made up of

A

lots of different hydrocarbons of different lengths

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6
Q

what can crude oil be separated into

A

fractions: simpler more useful mixtures containing hydrocarbons of similar lengths

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7
Q

what are the fractions of crude oil

A
  • gases
  • petrol
  • kerosene
  • diesel
  • fuel oil
  • bitumen
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8
Q

what is feedstock

A

raw materials

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9
Q

how are the fractions in crude oil separated

A

fractional distillation:
shorter hydrocarbons have lower boiling separate near top of column where it is cooler and vise versa

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10
Q

what are gases used for

A

domestic heating and cooking

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11
Q

what is petrol used for

A

fuel in cars

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12
Q

what is kerosene used for

A

fuel in planes

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13
Q

what is diesel used for

A

fuel in some cars and larger vehicles such as trains

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14
Q

what is fuel oil used for

A

fuel for large ships and some powerstations

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15
Q

what is bitumen used for

A

surface roads and roofs

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16
Q

what do the physical properties of crude oil depend on

A

how big the hydrocarbons in the fraction are

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17
Q

how does boiling point change in fractions of hydrocarbons

A

increases as hydrocarbon chains get longer. shorter chain have weaker intermolecular forces of attraction

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18
Q

how does ignition change in fractions of hydrocarbons

A

shorter chain hydrocarbons ignite easier

19
Q

how does viscosity change in fractions of hydrocarbons

A

longer chain hydrocarbons are more viscous

20
Q

how does colour change in fractions of hydrocarbons

A

longer chain hydrocarbons tend to be darker in colour

21
Q

how many bonds does a carbon atom form

A

4

22
Q

how many bonds does a hydrogen atom form

A

1

23
Q

what is an alkane

A

single covalent bond between all carbon atoms (saturated)
formula: C(n)C(2n+2)

24
Q

what is an alkene

A

have atleast one double covalent bond between carbon atoms (unsaturated)
formula: C(n)H(2n)

25
Q

what is a homologous series

A

a series of compound that:
- same general formula
- differ by CH2 of neighbouring compounds
- similar chemical properties
- gradual variation of physical properties

26
Q

what do oil fractions mostly contain

A

alkanes

27
Q

what is complete combustion

A

reaction between hydrocarbon and O2
when theres a plentiful supply of oxygen
is an exothermic reaction

28
Q

general formula for complete combustion

A

hydrocarbon + oxygen —-> carbon dioxide + water

29
Q

when does incomplete combustion occur

A

limited supply of oxygen (in appliances such as boilers)

30
Q

products of incomplete combustion

A

water, carbon dioxide, carbon monoxide, carbon (less O2)

31
Q

problems of carbon monoxide

A
  • colourless, odorless gas
  • binds to haemoglobin in RBC limiting O2 in blood stream
  • result in fainting, coma, even death
32
Q

problems of carbon (incomplete combustion)

A

soot: blacken buildings, clog pipes, reduce air quality, cause breathing problems

33
Q

acid rain

A
  • sulfur impurities in hydrocarbons oxidise and form sulfur dioxide when burnt
  • sulfur dioxide dissolves in water in clouds sulfuric acid that falls as acid rain
34
Q

effects of acid rain

A
  • corrodes metal and limestone weakening buildings
  • damages crops, plants and trees
  • kills fish (rivers and lakes too acidic to survive) and insects
35
Q

oxides of nitrogen

A
  • nitrogen and O2 from air react under high temperatures in car engines
36
Q

effects of oxides of nitrogen

A

harmful pollutants
cause photochemical smog
air pollution: difficulty breathing, headaches

37
Q

advantages of using hydrogen as a fuel

A
  • only waste product is water
  • renewable (obtained from water)
38
Q

disadvantages of using hydrogen as a fuel

A
  • hard to store
  • not widley avaliable
  • expensive to manufacture
  • special, expensive engine required
39
Q

what is cracking

A

taking a long chain hydrocarbon (alkane) and breaking it down into shorter more useful hydrocarbons (alkane and alkene)

40
Q

what are the two types of cracking

A

thermal and catalytic

41
Q

what is catalytic cracking

A
  • use high temp and a catalyst
  • catalyst speeds up the reaction
  • covalent bonds break and reform
42
Q

why are alkenes useful

A
  • used to make polymers
  • used as a starting material for useful chemicals
  • useful as feedstock for petrochemical industry
43
Q

thermal cracking

A
  • uses high temperatures of up to 750°c
44
Q

reasons for cracking

A
  • shorter chain hydrocarbons more useful and in higher demand but in less supply
  • longer chain hydrocarbon that there are more of in less demand can be cracked to meet supply of shorter chain hydrocarbons