carbs (c) Flashcards
why is starch unreactive and stable
anomeric carbon is involved in glycosidic bond formation, leaving few free anomeric hydroxyl groups
starch is composed of several hundreds to thousands glucose monomers. hence,
hence, it acts as a large store of carbon
how is amylose compact
amylose molecules are helical in shape
amylopectin is highly branched due to the presence of @(1,6) glycosidic bond. so??
hence amylopectin is compact and there are many free ends available for hydrolysis by amylase
how does starch not affect water potential of cells and living organism?
starch is large and insoluble
glycogen’s structure and adaptation to function is same as?
starch
how is ß(1,4) glycosidic bond formed and what’s the effect on cellulose’s structure
the alternate monomers are inverted to form the ß(1,4) glycosidic bond. hence, cellulose forms a long, unbranded straight chain.
how does cellulose provide high tensile strength?
3 points
- alternate ß glucose monomers are inverted and linked by ß(1,4) glycosidic bonds to form a straight unbranched and long chain.
- there is extensive hydrogen bonding between chains, forming rigid cross-links
- straight parallel chains are grouped into microfibrils which eventually associate to form macrofibrils
how is cellulose so stable?
2 parts
ß glucose units are linked by ß(1,4) glycosidic bonds which has a different molecular shape than @(1,4) glycosidic bonds in amylose and amylopectin.
since amylase can only hydrolyse the bonds found in starch and very few organisms produce cellulase, cellulose is stable
cellulose is L____ and I_____
large and insoluble