carbs (c) Flashcards

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1
Q

why is starch unreactive and stable

A

anomeric carbon is involved in glycosidic bond formation, leaving few free anomeric hydroxyl groups

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2
Q

starch is composed of several hundreds to thousands glucose monomers. hence,

A

hence, it acts as a large store of carbon

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3
Q

how is amylose compact

A

amylose molecules are helical in shape

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4
Q

amylopectin is highly branched due to the presence of @(1,6) glycosidic bond. so??

A

hence amylopectin is compact and there are many free ends available for hydrolysis by amylase

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5
Q

how does starch not affect water potential of cells and living organism?

A

starch is large and insoluble

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6
Q

glycogen’s structure and adaptation to function is same as?

A

starch

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7
Q

how is ß(1,4) glycosidic bond formed and what’s the effect on cellulose’s structure

A

the alternate monomers are inverted to form the ß(1,4) glycosidic bond. hence, cellulose forms a long, unbranded straight chain.

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8
Q

how does cellulose provide high tensile strength?

3 points

A
  1. alternate ß glucose monomers are inverted and linked by ß(1,4) glycosidic bonds to form a straight unbranched and long chain.
  2. there is extensive hydrogen bonding between chains, forming rigid cross-links
  3. straight parallel chains are grouped into microfibrils which eventually associate to form macrofibrils
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9
Q

how is cellulose so stable?

2 parts

A

ß glucose units are linked by ß(1,4) glycosidic bonds which has a different molecular shape than @(1,4) glycosidic bonds in amylose and amylopectin.

since amylase can only hydrolyse the bonds found in starch and very few organisms produce cellulase, cellulose is stable

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10
Q

cellulose is L____ and I_____

A

large and insoluble

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