Carboxylic Acids And Esters Flashcards
What are carboxylic acids?
They are a homologous series of organic acids which have the carboxyl (-COOH) functional group.
Physical properties of carboxylic acids
- They are very soluble in water.
- IMF increases down the group.
- Carboxylic acids dissolve in water to produce mobile ions, hence they are able to conduct electricity.
Chemical properties: Carboxylic acids have weak conductivity.
They are weak acid, they dissociate partially in water to form H+ ions.
Carboxylic acids reaction with metal
Products: Salt + hydrogen
Carboxylic acids reaction with metal carbonate
Products: Salt + carbon dioxide + water
Carboxylic acids reaction with base
Products: Salt + water
Carboxylic acids reaction with alcohols
Products: ester + water (condensation reaction, reversible)
What are esters?
Esters are sweet smelling, colourless liquids that are insoluble in water. They contain the -COO- functional group.
Esterification
Reagent: Alcohol, Carboxylic acid
Reaction conditions: Heat, concentrated sulfuric acid
Naming and Structural Formula of Ester
Naming: Alcohol + Carboxylic acid
SF: Carboxylic acid + Alcohol
Use of Esters
- In preparation of perfumes
- As artificial food flavourings
- In soap