Carboxylic acid derivatives Flashcards

1
Q

What is a carboxylic acid derivative?

A
  • A derivative of a carboxylic acid is a compound that can be hydrolysed to form the parent carboxylic acid
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2
Q

What do all carboxylic acid derivatives have?

A
  • they all have a common sequence of atoms in their structure called an acyl group
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3
Q

What is an acyl group?

A

R - C= O

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4
Q

What are all the carboxylic acid derivatives?

A
  • ester
  • acyl chlorides
  • acid anhydrides
  • amide
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5
Q

How do u name an ester?

A
  • remove the -oic acid suffix and replace it with -oate
  • the alkyl chain attached to the oxygen of the COO group is then the first word in the name
  • for example= methyl ethanoate
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6
Q

How do u name an acyl chloride?

A
  • an acyl chloride can be named by removing the -oic acid and replacing it with -oyl chloride
  • for example = propanoic acid turns to propanoyl chloride
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7
Q

How do you form an acid anhydride and how do u name one?

A
  • an acid anhydride is formed by removing water from two carboxylic acids
  • to name this you add anhydride to the carboxyl
  • For example = ethanoic anhydride
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8
Q

What are the three ways you can form an ester?

A
  1. From carboxylic acids
  2. From acyl chlorides
  3. From acid anhydrides
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9
Q

How do you form an ester from a carboxylic acid?

A
  • esterification
  • this is the process where an alcohol and a carboxylic acid react to form an ester
  • the alcohol is warmed with a carboxylic acid and a small amount of sulfuric acid which acts as a catalyst
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10
Q

Draw the reaction of an alcohol and an carboxylic acid (propanoic acid and ethanol)

A
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11
Q

How do you form an ester from an acyl chloride

A
  • reacting an acyl chloride with alcohol
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12
Q

Write the reaction of ethanoyl chloride and propan - 1 -ol

A
  • notes
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13
Q

How do you form an ester from an acid anhydride?

A
  • reacting an acid anhydride with an alcohol
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