Carbonate Sediments and Carbonate Rocks Flashcards
Difference between Siliciclastic and Terrigenous
- Siliciclastic is dominated by silicic fragments
- Terrigenous is made up of detrital material eroded under non-marine conditions from pre-existing rocks terranes
Intraclast
vs
Lithoclast
- Intraclast - intrabasinal origin
- Lithoclast - Extrabasinal origin
Spar vs Micrite
- Spar - can be calcite or aragonite. Coarser then micrite > 4 micrometers carbonate cement. Origing 1) preciptiation out of water as cemet. 2) recrystallization of micrite or othe carbonate grain
- Micrite- Cryptocrystalline carbonate mud. Origin is polygenic <4micrometers
Allochems
Broken off parts of organisms. the most commun source of carbonate clasts in the marine environment is biological. Many marine invertebrates and certain very commun algae produce precipitated carbonate structures (shells, plates,etc..). Upon death of the organism, these grains (or Allochems) become part of the fabric of the carbonate rocks.
Orthochem
The term used in the Folk classification to describe the micrite matrix and sparry calcite (sparite) cement in limestones.
Allochem Wiki def.
Allochem is a term introduced by Folk[1] to describe the recognisable ‘grains’ in carbonate rocks. Any fragment from around ½mm upwards in size may be considered an allochem. Examples would include ooids, peloids, oncolites,pellets, fossil or pre-existing carbonate fragments.
How ooids are formed?
Ooids form in areas where marine currents (for exemple, tidal currents) keep grains in motion.
Hermatypic
Hermatypic corals are those corals in the order Scleractinia which build reefs by depositing hard calcareous material for their skeletons, forming the stony framework of the reef.
what type of relationship hermatypic corals have with yellow-brown algae?
Algae provide nutrition (O2, glucose, amino acids)
Corals provide living space and easte nutrients (which used by algae) CO2, NO-3, NH+4 …
What is the major importance of corals in the ecosystem?
- It creates new environments, so sedimentary structures are going to be different as well.
- It changes the destribution of light and energy of the environment
which organisms play a important role on the biomineralization of calcium carbonate?
Foraminifera, Bryozons, Molluscs, Echinoderms, Corals, pteropods, coccolitophores
which 2 organisms are the most important on the biomineralization of calcium carbonate?
Foraminifera and Coccolithopores
Carbonates belong to a group of rocks formed by……… and/or………….reactions
…..precipitation….biochemical…
Carbonates belong to a group of rocks formed by precipitation. Which other rocks are also included in the cabonates group?
- Evaporite (salt, gypsum, etc..)
- Chert (ilica) which also precipitates
- Carbonaceous rocks (coal)
- Others (phosphorites, iron-rich rocks)
What controls the inorganic preciptation of calcite in water?
cpH controls calcite precipitation via the amount of CO2 disolved in water.
DEGASSING (Release of CO2)
- Increase in temperature (high temperature)
- Decrease in pressure (think of a coke open)
- Agitation
Note: you want shallow, warm and agitated (waves) environment.
What type of environmet facilitates precipitation of Calcite?
A shallow, warm and agitated (waves) environment.
Coastal marine
The chance of calcite being just CaCO3 is very ………..
They can also be made with ………….. and……………
Low
Mg and Fe
……………is very important when talking about carbonates.
Biology
Calcite vs Aragonite structure
Calcite is rhomboheadral
Aragonite is orthorhombic
In termes of crystal structure and chemical composition, aragonite is a …………………… of calcite.
Polymorphic
what happens with calcite in an acidic environment?
It dissolves
Name it:
1- CaCO3
2- FeCO3
3- MgCO3
4- CaMg(CO3)2
1- calcite / aragonite
2-siderite
3-magnesite
4- dolomite
How can you minimize the presence of carbonic acid in a aqueous environment?
Degassing:
- Increase temperature
- Decrease pressure
- Agitation
……………….reactions are responsable for the majorite of carbonate precipitation in an equaeous environment
BIOGENIC
The majority of carbonates precipitation is ……………..
Biogenic
Organic carbonate deposition is dictated by whatever makes the…………. of those carbonate secreating organisms to ……………
Biology/ succeed
What kind/s of biogenic processes are responsable for most carbonates precipitation?
- Direct precipitation
- Removal of CO2 linked to photosynthesis
- Bacterially mediated
Bacterially mediated (biologically induced/controlled and linked to physiological processes)
The distribution of carbonate-secreating algae is governed by……(6- T,S,L.a,C.s,Sub,F.a)….
- Temperature
- salinity
- light availability (depth)
- Current strength
- Substrate
- Food availability
Carbonate precipitation: The key controls are factors that limit/enhance the distribution/growth of particular organisms.The controls are:
- Temperature
- Salinity
- Light availability (depth)
- Current strength
- Substrate
- Food availability
What are the major controls on calcite precipitation?
- Inorganic reaction
- Biogenic
- Hermatypic corals(reef building)
- Water depth (CCD)
- Evolution and distribution of organisms
What is our current mode of carbonate sedimentation in the oceans?
Arogonitic + High-Mg calcite
Hard CaCO3 skeletons are secreted by……………………corals, which live in ……………….. with yellow -brown …………
Hermatypic/ symbiosis/ algae
How the symbiotic relationship of corals and yellow-brown algae works?
The algae provides nutition and the corals provide living space and waste nutients (which are used by algae)
The algae provides ………….. and the corals provide……………. and ………………….. (which are used by algae)
nutition/ living space/waste nutients
what are the major two impacts corals have in the environment?
They change/alter the distribution of light and energy in the environment
Corals create new…………………,so we can expect ………………..to be also different.
environments/ sedimentary structures or deposition
CCD
Calcite compensation depth (CCD) is the depth in the oceans below which the rate of supply of calcite (calcium carbonate) lags behind the rate of solvation, such that no calcite is preserved.
or Calcite dissolves at much higher rates than it can precipitates
CCD: Dissolution of……………….(first) then ……………. increases with ………………….and ……………….
Aragonite/Calcite
Depth/temperature
Below CCD ,……………….starts dissolving, but not…………………
Carbonates/ silicates
below CCD you can find …………….rich sediments.
Silica
During green house Earth, the CCD will be ………………..then todays compasation depth (4kms) . During icehouse Earth, the CCD will be ………….then today depth. If we freeze Earth, then the CCD will be…………… than todays depth.
Lower (increase temp - increase pH)/ Same (we are living in a icehouse earth)/ higher (Decrease temp is related to lower pH)
The greater the depth, the more. concentration of…………, the more………… acid, the lower the………………
CO2/ Carbonic acid/ pH
Can you find calcareous organisms in the bottom of the ocean (greatre than 4kms)?
No, this is below the carbonate compensation zone. the calcite available would dissolve leaving just Silicious ooze (forms chert).
what is responsable for the great majority of silicious ooze in the bootom of the oceans (abyssal or greater than 4km)?
Wind-blown dust. (remember the sahara blowing silicious particle in the oceans)
……………ooze forms carbonate mudstone and ……………….ooze forms chert.
Calcareous/ siliceous