carbon cycle Flashcards
examples of carbon compounds
- carbon dioxide, found in the atmosphere, oceans and soils
- methane, found in the atmosphere, soils, oceans and sedimentary rock
- calcium carbonate, found in calcareous rock (e.g.limestone), oceans, shells and skeletons
- hydrocarbons, fossil fuels in gas and liquid form found in sedimentary rock
- biomolecules, produced by living things, proteins, carbohydrates and fats
a systems approach
- global carbon cycle is a closed system, the amount of carbon is constant
- there are local sub systems of the carbon cycle that are open systems
- sub systems characterised by inputs, outputs, stores and transfers
- operates between major carbon stores in organic and inorganic form
short term stores of carbon
- terrestrial ecosystems (biosphere), carbon dioxide taken from atmosphere through photosynthesis, carbon is stores organically. Rapid interchange with atmosphere
- atmosphere, carbon is stored as greenhouse gases
- oceanic surface (hydrosphere), rapid exchange with the atmosphere, includes physical and biological processes
- terrestrial soil (pedosphere), microorganisms break most biomass and respire producing carbon dioxide. Amount of time in the store depends n climate
flux
the process by which carbon movesbetween stores
fast carbon cycle
- rapid transfer of carbon compounds over years, decades and centuries
- involves the transfer of organic carbon via living things taking place between the biosphere, pedosphere and atmosphere
- involves the transfer of inorganic carbon between the ocean and the atmosphere
slow carbon cycle
- transfer of carbon compounds over extensive cycles (hundreds of millions of years)
- involves the long term sequestration of the remains of marine creatures and terrestrial forests as fossil deposits of oil, gas and coal
- involves the long term transfers of carbon between the atmosphere and hydrosphere and then the carbon rich sedimentary rocks of the lithosphere. Recycled via tectonic activity
key processes in the geological carbon cycle
- mechanical, biological and chemical weathering of rocks
- decomposition of plants and animals
- transportation of ions in rivers to the ocean, where they are deposited
- sedimentation over millennia
- metamorphosis of sedimentary rocks
composition of oil and natural gas
- formed from the remains of tiny aquatic animals and plants
- occur in porous rocks, migrating up through the crust until meeting caprocks
- natural gas such as methane is made up of the fractions of oil molecules, so small they are in gas form not liquid, usually found with crude oil
composition of coal
-formed from the remains of trees, ferns and other plants
- anthracite is the hardest coal that contains the most carbon so has a higher energy content
- bituminous coals are next in hardness and carbon content
- soft coals such as lignite and brown coal are the major global source of energy supplies but are lower in carbon and emit more carbon dioxide
- peat is the stage before coal and is an important energy source
chemical weathering in the geological carbon cycle
- in the atmosphere, water reacts with atmospheric CO2 and carbonic acid forms
- as this is weakly acidic, once the water reaches the surface as rain it reacts with surface minerals, slowly dissolving them into their component ions
- transportation of calcium ions by rivers into oceans
- calcium ions combine with bicarbonate ions in oceans to form calcium carbonate and calcite
- deposition and burial turns the calcite sediment into limestone
- subduction of the sea floor under continental margins by plate tectonics
- some of the carbon rises back up to the surface within heated magma then is ‘deassed’ as CO2 and returned to the atmosphere. Tectonic uplift can also expose previously buried limestone
negative feedback regulating the carbon cycle
- increase in volcanic activity
- rise in Co2 emissions and loss of carbon from rocks
- temperature rises
- more uplift of air, condensation and rain
- more chemical weathering and erosion of rocks
- more ions then deposited on ocean floors
- more carbon stored in rocks
- the cycle takes a few hundred thousand years to rebalance
volcanic outgassing
- active or passive volcanic zones associated with tectonic late boundaries
- hot springs and geysers at places with no current tectonic activity
- direct emissions from fractures in the earth’s crust
how carbon fluxes vary
- diurnally, the fluxes are positive during the day (net carbon movement from the atmosphere to the ecosystem) and negative at night (net movement of carbon from the ecosystem to the atmosphere) as photosynthesis only occurs i the presence of solar energy
- seasonally, in the Northern hemisphere, atmospheric CO2 levels increase in winter as there is less vegetation and growth. In Spring CO2 concentrations drop as plants start growing and photosythesising
capacity of soil to store carbon determined by
Climate:
- dictates microbial activity
- rapid decomposition occurs in hot places
- high rainfall means increased potential carbon storage
Soil type:
- clay rich soils have a higher carbon content than sandy soils as clay protects carbon from decomposition
- loss of carbon through cultivation and disturbance
Sequestration of Carbon
- Sequestering is the movement of carbon into carbon stores which can lower the amount of carbon dioxide in the atmosphere
- Photosynthesis (by land based plants and phytoplankton) is the main process responsible for sequestering carbon from the atmosphere
how is the movement of carbon within oceans is controlled
- Vertically by carbon cycle pumps
- Horizontally by thermohaline circulation
ocean sequestration - biological pump
- The biological cycle sequesters carbon in the ocean through photosynthesis by phytoplankton and other marine animals which convert CO2 into organic matter
- This acts as a biological pump transporting carbon from the oceans’ surface to the intermediate and deep ocean stores
- As the biological organisms die, their dead cells, shells and other parts sink into the mid and deep water
- Also, the decay of these organisms releases carbon dioxide into the intermediate and deep water stores
ocean sequestration - carbonate pump
- Relies on inorganic carbon sedimentation
- When organisms die and start to sink, many shells dissolve before they reach the ocean floor entering the deep ocean currents
- CO2 absorbed by the oceans from the atmosphere forms carbonic acid which in turn reacts with hydrogen ions to form bicarbonates and then further reactions form carbonates which are stored in the upper ocean
- Some organisms use these carbonates to make their shells or skeletons
- When these organisms die some material sinks to the ocean floor and forms the sea bed sediment store
- Over time, through chemical and physical processes, the carbon is transformed into rocks such as limestone
- This process locks up carbon in the long-term carbon cycle and does not allow an easy return to the ocean surface and so prevents possible venting into the atmosphere as the physical pump does
ocean sequestration - physical pump
- Considered the most important transfer
- CO2 is absorbed by the ocean’s surface through diffusion
- Dissolved CO2 is then taken from the surface down to the intermediate and deep ocean stores through downwelling currents
- The thermohaline circulation then distributes the carbon around the planet
- Cold water absorbs more CO2, therefore, as the equatorial waters move toward the poles, more CO2 is absorbed
- Salinity increases at the same time as some of the pure ocean water freezes, making the water denser, therefore, the water sinks (downwelling) taking CO2 from the ocean’s surface to the deep ocean stores
- Allowing more diffusion to occur at the surface and helping to regulate the carbon stored in the atmosphere
However, there is also the upwelling of carbon from intermediate and deep oceans to the surface oceans - Through upwelling currents and turbulence created by surface winds, previously stored carbon in the intermediate and deep ocean stores, return to the ocean’s surface and then back into the atmosphere
ocean acidification - chemical pathway
- more CO2 added to the atmosphere through human activities such as fossil fuel combustion
- the Co2 us dissolved in seawater, causing the balance of chemical reactions to shift and resulting in more hydrogen ions (increasing acidity)
- more hydrogen ions lead to a lower concentration of carbonate ions which are necessary for shell and skeleton growth for certain marine organisms
ocean acidification - chemical pathway
- phytoplankton converts CO2 into organic carbon through photosynthesis
- coastal nutrient runoff from agriculture, rising temperatures and CO2 levels increase amount of phytoplankton
- larger marine organisms consume the plankton and release CO2 through respiration or decomposition, making the ocean more acidic
- upwelling brings the acidic water from the descended decaying organisms to the surface
thermohaline circulation
- the global system of surface and deepwater ocean currents driven by temperature and salinity differences between oceans
human impact on the carbon cycle
- depleted and enhanced stores
- sped up fluxes
- increased atmospheric carbon, enhancing the greenhouse effect
- sped up carbon release from the slow carbon cycle e.g. extracting hydrocarbon
anthropogenic factors affecting the carbon cycle
- burning fossil fuels, releasing greenhouse gases into the atmosphere
- land use change, agriculture releases carbon, machinery and fertilisers, livestock
- deforestation, burning, decreasing carbon store and photosynthesis
- urbanisation, by replacing vegetation and soil and producing cement
human impacts, implication for the climate
- on a global and regional scale
- rising global temperature and sea levels
- at a global scale, rising temperatures will lead to more evaporation, meaning more precipitation
- global shifts in weather patterns and more extreme intense and frequent weather events including floods and droughts
- at a regional level, some areas will be hotter and drier, some wetter, and some will have more rain instead of snow
- alterations in ocean temperatures and salinity from global warming will affect thermohaline currents by slowing or reversing the north atlantic drift
human impacts, implications for ecosystems
- global warming will have a direct effect on species distribution and habitat change
- affect population sizes and ultimately lead to extinctions
- marine organisms will be affected by lower oxygen levels, rising sea temperatures and ocean acidification
- arctic and coral ecosystems most at risk
- cool, moist regions could provide habitats for additional species as temperatures rise
human impacts, implications for the hydrological cycle
- increased evaporation and precipitation and changes in precipitation type
- permafrost will melt releasing a large amount of methane, creating a positive feedback loop
- reduced sea ice, icecaps and glaciers
- direct effect on El Nino
the greenhouse effect
- the natural temperature control system of the earth that relies on greenhouse gases
- concentration of atmospheric carbon strongly influences the greenhouse effect
- solar radiation passes through the atmosphere
- 30% reflected by clouds, aerosols and gases in the atmosphere
- 70% absorbed
- 70% of surface absorption re-radiated into space as longwave radiation
- an increase of greehouse gases means more longwave radiation is trapped in the atmosphere, increasing the earth’s temperature