Carbohydrates Flashcards
Polymer
Chains of repeating monomer units
Monosaccharides (monomers)
Sweet tasting, soluble substances
E.g. Glucose
Monosaccharides join by together by condensation reactions and forms a glycosidic bond.
Disaccharides (polymers)
Two monosaccharides joined
E.g. a glucose + a glucose = maltose
Can break into monosaccharides by adding water (hydrolysis reaction) and breaks glycosidic bonds
Polysaccharide
Many monomers joined in condensation reactions
Insoluble - good for storage
E.g. Starch
Can break into monosaccharides by adding water (hydrolysis reaction) and breaks glycosidic bonds
Common disaccharides
Maltose (a glucose + a glucose)
Sucrose (a glucose + fructose)
Lactose (a glucose + galactose)
Monomers
Individual molecules
Reducing sugars
All monosaccharides and some disaccharides.
Can donate electrons (reduce) other chemicals
E.g. Maltose, glucose
Non-reducing sugars
The other disaccharides and all polysaccharides.
Can’t donate electrons.
E.g. Sucrose
Test for reducing sugar
Add Benedict’s reagent and heat
Turns red/orange/yellow/green
Test for non-reducing sugar
Add Benedict’s and heat, it will remain blue
Add hydrochloric acid, which hydrolyses it
Add sodium hydrogen carbonate sodium to neutralise the HCl
Then do the test for a reducing sugar
Test for starch (polysaccharide)
Add iodine solution
Turns blue/black
Viking tubing experiment
Points to consider:
Protein molecules are too large to pass through the tubing
Starch molecules pass through tubing
Once starch is hydrolysed to maltose it can pass through the tubing
Starch (made of a glucose chains)
Branched / coiled / alpha helix, so makes the molecule compact and can fit into a small space.
It is insoluble so it stops osmosis and doesn’t affect water potential.
A long chain so it can’t cross the cell membrane.
It’s a polymer of alpha glucose so provides glucose for respiration.
Branched so glucose is easily released in respiration (means more ends for enzyme action)
Monomers linked by glycosidic bonds through condensation reactions.
Cellulose (B glucose chains)
Gives the cell strength because:
Long, unbranched (straight) chains of B glucose
Several chains lie side by side and form micro fibrils
Hydrogen bonds hold these chains together
Hydrogen bonds are strong in large numbers
Cellulose only has 1,4-glycosidic bonds
Glycogen (alpha glucose chains)
Shorter, more branched chains than starch
Can be hydrolysed to monomers more easily (quicker energy)
Spiral shape means it’s more compact and can fit into a small space
Coiled as opposed to straight
Glycogen has 1,4 and 1,6-glycosidic bonds