Carbohydrates Flashcards

1
Q

Physiological roles of carbohydrates

A

1) energy source
2) energy storage
3) structural roles
4) cellular communication
5) information transfer

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2
Q

Monosaccharides

A

smallest unit of carbohydrate structure

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3
Q

Disaccharides

A

two monosaccharides covalently linked together through a glycosidic bond

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4
Q

oligosaccharides

A

polymers of 3-20 monosaccrides

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5
Q

polysaccharides

A

polymers of more than 20 monosaccrides

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6
Q

glycoconjugates

A

linked to proteins or lipids

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7
Q

Empirical formula of carbs

A

(CH2O)n

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8
Q

Two major classes of carbs

A

aldoses, ketoses

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9
Q

formula for steroisomers

A

2^n

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10
Q

epimers

A

are sugars that differ at only one of several chiral centers

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11
Q

reaction of alcohol with an aldehyde

A

forms a hemiacetal

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12
Q

reaction of alcohol with a ketone

A

forms a hemiketal

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13
Q

pyranose

A

six-carbon sugar

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14
Q

furanose

A

five-carbon sugar

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15
Q

which carbon becomes chiral

A

anomeric

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16
Q

alpha

A

hydroxyl of anomeric carbon is below the plane of the sugar

17
Q

beta

A

if hydroxyl of anomeric carbon is above the plane of the sugar

18
Q

mutarotation

A

when the alpha and beta configurations interconvert in solution

19
Q

monosacchrides are _____

20
Q

the carbonyl group is _______ to a carboxyl group

21
Q

the end of the sugar with the carbonyl carbon is the ____

A

reducing end

22
Q

glycosidic bond

A

primary structural linkage in all polymers of monosaccrides

23
Q

homopolysacchrides

A

polymers containing a single type of monosacchrides

24
Q

heteropolysacchrides

A

polymers containing more than one type of monosacchrides

25
starch
mixture of amylose and amylopectin
26
amylose
linear polymer of glucose resides through alpha (1-4) bonds
27
amylopectin
consists of alpha (1-4) linked glucose residues with alpha (1-6) branch points every 24-30 residues
28
glycogen is present in which cells
all cells but mostly in skeletal muscle cells and the liver
29
how does glycogen compare to amylopectin
structurally the same but with more branch points
30
what does greater branching do
more rapid mobilization
31
what is the primary component of plant cells walls
cellulose
32
can cellulose be cut by amylose
no
33
what is chitin
what makes up exoskeletons
34
difference between chitin and cellulose
replacement of hydroxyl group at C2 with acetylated amino group
35
ground substance
exracellular space in tissues that has a gel-like material in the matrix
36
what does ground substance do
holds cells together, provides a porous pathway for the diffuion of nutrients/waste prodeucts and serves a cushioning function
37
glycosaminoglycan
extracellular matrix is a meshwork of fibrous proteins and heteropolysacchrides
38
proteoglycans
covaently linked glycosaminoglycans to extrcellular proteins