Carbohydrates Flashcards
Physiological roles of carbohydrates
1) energy source
2) energy storage
3) structural roles
4) cellular communication
5) information transfer
Monosaccharides
smallest unit of carbohydrate structure
Disaccharides
two monosaccharides covalently linked together through a glycosidic bond
oligosaccharides
polymers of 3-20 monosaccrides
polysaccharides
polymers of more than 20 monosaccrides
glycoconjugates
linked to proteins or lipids
Empirical formula of carbs
(CH2O)n
Two major classes of carbs
aldoses, ketoses
formula for steroisomers
2^n
epimers
are sugars that differ at only one of several chiral centers
reaction of alcohol with an aldehyde
forms a hemiacetal
reaction of alcohol with a ketone
forms a hemiketal
pyranose
six-carbon sugar
furanose
five-carbon sugar
which carbon becomes chiral
anomeric
alpha
hydroxyl of anomeric carbon is below the plane of the sugar
beta
if hydroxyl of anomeric carbon is above the plane of the sugar
mutarotation
when the alpha and beta configurations interconvert in solution
monosacchrides are _____
reducing
the carbonyl group is _______ to a carboxyl group
oxidized
the end of the sugar with the carbonyl carbon is the ____
reducing end
glycosidic bond
primary structural linkage in all polymers of monosaccrides
homopolysacchrides
polymers containing a single type of monosacchrides
heteropolysacchrides
polymers containing more than one type of monosacchrides