carbohydrates Flashcards
what are monosaccharides and the 2 examples
they are sugars and there are composed of aldoses and ketoses
what is the difference between aldoses and ketoses
ketoses have a double bond (ketones) compared to aldoses ( aldehyde)
how can you distigush an anomers ?
1) alpha OH down oposite of 2nd carbon ch2oh
2) Beta anomer OH is up same side of C2OH
what is the difference in aldose and ketoses cyclic forms
aldose , 2 OH on right side
ketose cyclic , all OH on right side
what are the difference between reduced and non redcue sugars ?
reduced surgars of no double O
oxidixezed sugar have a ketone or carbozylic acid
how can you make amino sugars?
by moodifying de oxy ribose at the 3 or 2 carbon with an amino group
what are glycosidic bonds ?
anomeric OH + alcohol (OH) form a bond
what are the 3 storage poly saccarindes and where are they found
- amylose
- amylopectin
- glycogen
amylose and amlyopectin make up starch in plants
glycogen found in granuels within cells
what is made up of amylose and how is is it linked
Glucose and linked through and alpha 1,4 linkage
what is amylopectin made up of and how is it linked
glucose and it is linked with branched a 1,4 glucose and alpha 1,6 branches
how is glycogen branched ?
via 1,4 alpha is more branched than amylopecitn
what are the 2 structural poly saccharides ?
cellulose and chitin
what is cellulose composed of and how it is linkes and where is found
glucose and linked through beta 1,4 molecule, cell wall of plants
what is chitin made up of and what is its linked and where is it foundeed
glucose and beta 1,4 linkage and in arthoprod exo skeleton
what is the difference between beta 1,4 and alpha 1,4 linage
beta makes structual alpha makes storagre alpha linkage is stronger
what 3 AA are found in glycoprotein?
Asn, THR and Ser
what links gylcoprotein
hylarunic acid
what are 4 other things poly saccharids contribute to ?
- ECM
- Glyoamino glycans
- Glycoprotein
- connective tissue proteoglycans
how is a bacterial cell wall linkes
beta 1,4
what are enatiomers , epimers and diastomers
enan - mirror
epimoer - differ at 1 stereo centre
dias- differe at multiple sites