Carbohydrates Flashcards
carbohydrate’s role in tissue
- contribute to metabolism by acting as fuels
- structural role of biological structures
elements that make up carbohydrate’s
carbon, hydrogen, oxygen
2 types of carbohydrates based on carbonyl group
aldoses: aldehyde group
ketoses: keto group
types of carbs based on # of carbons
3 C’s: trioses
5 C’s: pentoses
6 C’s: hexoses
trioses
simplest monosaccharide (carb)
- either an aldotriose or ketotriose
chiral carbon
has four different atoms or groups attached to it, all monosaccharides contain at least one chiral center
stereoisomers
differ in their 3-D orientations, # of possible stereoisomers w/ a chiral centers = 2^n
enantiomers
special isomers that are mirror images of each other
D & L stereoisomers
based on the chiral center furthest from the carbonyl group, either D or L
what stereoisomer are naturally occurring sugars
they are D stereoisomers
cyclic monosaccharides
tend to be 5+ carbon monosaccharides, have an anomeric carbon, and can be in the alpha or beta configuration
anomeric carbon definition
additional asymmetric carbon in a cyclic structure
enzyme’s with cyclic monosaccharides
they can distinguish between alpha and beta configurations
name of 5-member and 6-member closed ring
5-member: pyranose
6-member: furanose
glycosidic bond
formed when the anomeric carbon of one sugar reacts with the hydroxyl group of another, gives off water as well