Carbohydrates Flashcards

1
Q

carbohydrate’s role in tissue

A
  1. contribute to metabolism by acting as fuels
  2. structural role of biological structures
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2
Q

elements that make up carbohydrate’s

A

carbon, hydrogen, oxygen

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3
Q

2 types of carbohydrates based on carbonyl group

A

aldoses: aldehyde group
ketoses: keto group

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4
Q

types of carbs based on # of carbons

A

3 C’s: trioses
5 C’s: pentoses
6 C’s: hexoses

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5
Q

trioses

A

simplest monosaccharide (carb)
- either an aldotriose or ketotriose

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6
Q

chiral carbon

A

has four different atoms or groups attached to it, all monosaccharides contain at least one chiral center

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7
Q

stereoisomers

A

differ in their 3-D orientations, # of possible stereoisomers w/ a chiral centers = 2^n

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8
Q

enantiomers

A

special isomers that are mirror images of each other

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9
Q

D & L stereoisomers

A

based on the chiral center furthest from the carbonyl group, either D or L

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10
Q

what stereoisomer are naturally occurring sugars

A

they are D stereoisomers

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11
Q

cyclic monosaccharides

A

tend to be 5+ carbon monosaccharides, have an anomeric carbon, and can be in the alpha or beta configuration

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12
Q

anomeric carbon definition

A

additional asymmetric carbon in a cyclic structure

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13
Q

enzyme’s with cyclic monosaccharides

A

they can distinguish between alpha and beta configurations

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14
Q

name of 5-member and 6-member closed ring

A

5-member: pyranose
6-member: furanose

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15
Q

glycosidic bond

A

formed when the anomeric carbon of one sugar reacts with the hydroxyl group of another, gives off water as well

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16
Q

2 function of complex sugars

A

structural and storage

17
Q

carbohydrate glycosidic bonds to non-carb structures

A

proteins (glycoproteins)
lipids (glycolipids)
nitrogenous bases (nucleotides)

18
Q

2 glycosidic linkage

A

N-glycosidic linkage
O-glycosidic linkage

19
Q

glycogen

A

multibranched polysaccharide of glucose, energy storage polysaccharide in animals

20
Q

glycogen function in muscle and liver

A

muscle: energy reserve for exercising muscles
liver: supplies glucose to the tissues via blood in the absence of dietary glucose

21
Q

Glycogen structure

A
  • joined by alpha 1-4 glycosidic bonds, with branches formed by alpha 1-6 glycosidic bonds
  • exists as a large spherical granule
22
Q

oligosaccharides

A

short chain of monosaccharides
- usually attached to proteins

23
Q

carbohydrates in the cell membrane

A

exclusively on the external side of the membrane bilayer, attached to proteins or lipids forming glycoproteins/glycolipids

24
Q

Hemoglobin A1C

A

is glycated hemoglobin A, continuous process in RBC’s