Carbohydrates Flashcards

1
Q

Monomer

A

single-molecule; small chemical unit that makes up a polymer by forming bonds

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2
Q

Polymer

A

A long chain of monomers chemically bonded together.

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3
Q

3 Examples of monomers

A
  • amino acids
  • monosaccharides
  • nucleotides
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4
Q

3 Examples of polymers

A
  1. Carbohydrates
  2. Proteins
  3. Nucleic Acids
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5
Q

Condensation reaction

A

A reaction in which 2 monomers become chemically bonded to each other to form a polymer through the loss of a water molecule

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6
Q

Hydrolysis reaction

A

The addition of a water molecule to break down a polymer into monomers by breaking a chemical bond

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7
Q

All carbohydrates contain

A

carbon, hydrogen, oxygen

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8
Q

Carbohydrates general formula

A

(CH2O)n

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9
Q

The 3 important monosaccharides

A

glucose, fructose, galactose

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10
Q

Isomer

A

compounds with the same chemical formula but different structures

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11
Q

Alpha and Beta glucose

A

H and OH swapped on Carbon 1.

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12
Q

Maltose equation

A

alpha glucose + alpha glucose

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13
Q

Sucrose equation

A

glucose + fructose

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14
Q

Lactose equation

A

glucose + galactose

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15
Q

Test for reducing sugars

A

Benedict’s test.

Add 2cm cubed of test solution.

Add to your solution, an equal amount of Benedict’s solution,

Heat in a water bath and if reducing sugars are present the benedicts will turn brick red.

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16
Q

Test for non-reducing sugars

A

If negative (stays blue), hydrolyse the substance with HCl

Boil

Neutralise with NaOH

Add Benedict’s

Brick red precipitate indicates non-reducing sugar.

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17
Q

Polysaccharides

A

Polysaccharides are formed when more than two monosaccharides are joined together by condensation reactions and glycosidic bonds.

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18
Q

Why is starch used as an energy molecule?

A

Starch is insoluble so it doesn’t affect the water potential.
Starch can be compact so it can be stored in a small volume.

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19
Q

What type of bond between monomers does starch have?

A

1-4 glycosidic bonds in amylose

1-4 and 1-6 in amylopection

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20
Q

What type of bonds between monomers does cellulose have?

A

1-4 glycosidic bonds

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21
Q

What type of bonds between monomers does glycogen have?

A

1-4 and 1-6 glycosidic bonds

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22
Q

What monomers is starch made from?

A

Alpha Glucose

23
Q

What monomers is cellulose made from?

A

Beta glucose

24
Q

What monomers is glycogen made from?

A

Alpha glucose

25
Structure of starch
Made of 2 polymers Amylose - Unbranched Helix Amylopecctin - A branched molecule
26
Structure of cellulose
Polymer forms long, straight chains Chains are held in parallel by many hydrogen bonds to form fibrils
27
Structure of glycogen
A highly branched molecule
28
How does starch structure lead to function?
Helix can compact to fit a lot of glucose in a small space
29
How does cellulose structure lead to function?
Many hydrogen bonds provide collective strength Insoluble - Wont affect water potential
30
How does structure of glycogen lead to function?
Branched structure increases surface area for rapid hydrolysis back to glucose Insoluble - Wont affect water potential
31
Name the 4 colours benedicts reagent displays with increasing concentrations of reducing sugars.
Blue Green Orange Brick Red
32
Before testing with benedicts reagent what must be done to sample suspected of being a non reducing sugar?
BOIL with HCl then add NAOH to neautralise
33
When testing for reducing sugars what temperature should the experiment be carried out at?
100 degrees celcius
34
What is the test for a plant storage polysaccharide?
Test for starch Add iodine dissolved in potassium iodide Blue/Black - starch present
35
What feature of polysaccharides makes them most suitable as a storage molecule?
Too large - Cannot leave the cell Coiled/Helical - Compact Insoluble - No osmotic effect
36
What are microfibrils?
Small components in cell walls with long chains of monomers held in parallel by hydrogen bonds to provide strength in cell wall
37
Where is starch located?
Plants
38
What is starch function?
Energy storage
39
What features help starch with energy storage?
Insoluble Highly branched Coiled
40
Where is glycogen found?
Liver Muscle cells
41
What is glycogen function?
Energy storage
42
What features help glycogen with energy storage?
Insoluble Compact Large Highly branched
43
What are the bonds in cellulose chains?
Hydrogen bonds
44
Which features help cellulose gain strength?
Microfibrils Long straight unbranched chains
45
What bonds are between individual beta glucose monomers in cellulose?
Glycosidic bonds
46
What is the purpose of a 1-4 bond?
Linear polymer formation
47
What is the purpose of a 1-6 bond?
Creates branched structure
48
Structure of amylose?
Unbranched polymer
49
Unique characteristic of amylose?
Coils into a helix
50
Advantage of unique characteristic of amylose?
Allows compact storage in small spaces
51
Structure of amylopectin?
Branched polymer
52
Key benefit of amylopectin structure?
Larger surface area
53
Enzymatic interaction of amylopectin?
More enzyme attachment points for glucose hydrolysis
54
What is the significance of polysaccharides being insoluble?
No impact on cell water potential No effect on osmosis