Carbohydrates Flashcards

1
Q

Mirror image stereoisomers are called _______

A

Enenatiomers

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2
Q

It is the simplest ketose and it does not have a chiral
carbon?

A

dihydroxyacetone

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3
Q

How many chiral carbons that glyceraldehyde have?

A

1

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4
Q

Number of stereoisomers that the fructose has?

A

8

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5
Q

The only non-reducing sugar among disaccharides

A

Sucrose

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6
Q

Which of the following polysugars is classified as homosugar
and a storage polysaccharide in man and animals?

A

Glycogen

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6
Q

The sugar unit of Lactose

A

galactose and glucose

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6
Q

It is the configuration of the glycosidic linkage of sucrose?

A

α- (1->2)

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7
Q

Polysugar that aims in the formation of normal stools and
helps relieve constipation

A

Cellulose

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8
Q

The only heteropolysaccharides that is non-sulfated is:

A

Hyaluronic acid

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9
Q

Glucose and mannose are epimers at what carbon atom?

A

Carbon - 2

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10
Q

Which simple sugar does starch and glycogen come from?

A

Glucose

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11
Q

Which polysugar is built for rapid glucose storage and is released
when glucose is needed?

A

glycogen

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12
Q

Which of the following is a polysugar/heteropolysaccharide?

A

dermatan sulfate

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13
Q

What are the epimers of glucose?

A

galactose and mannose

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14
Q

This non-reducing sugar has no mutual rotation property

A

sucrose

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15
Q

D-glucoronate and N-acetylglucosamine

A

hyaluronan

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16
Q

This heterosugar is a component of bone cartilage and the cornea

A

chondroitin sulfate

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17
Q

When D-glucose reacts with phenyl hydrazine, a crystalline
compound with a same needle shape is obtained

A

osazones

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17
Q

When glucose gets reduced, it becomes

A

sorbitol

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18
Q

What sugar is abundantly present in honey?

A

fructose

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19
Q

Which of the following is a Fructosan?

A

inulin

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20
Q

sugar that has 6 carbons and ketone group as its
functional group?

A

fructose

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21
Q

Which polysugar is absent in the blood group?

A

mannose

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22
Which of the following is an anticoagulant?
heparin
23
Most ketosis have this ketotriose as their parent compound
Dihydroxyacetone Dihydroxyacetone or DHA is the simplest ketose (ketotriose). It is the parent compound of ketosis
24
A carbon atom to which 4 different groups are attached to is called a _____ carbon.
Chiral A chiral carbon or an asymmetric carbon atom is a carbon atom that is attached to 4 different groups.
25
How many chiral carbons does dihydroxyacetone have?
None
26
If fructose has 3 chiral carbons, how many possible stereoisomers can it have?
8 Formula for stereoisomers is x=2^n x= 2^3 = 2x2x2 = 8
27
Epimers of glucose are:
Galactose and mannose
28
________ is an example of nonose (9 carbons).
Sialic acid
29
Mirror image stereoisomers are called ______
Enenatiomers
30
Which sugar is a ketose and is the sweetest sugar?
Fructose
31
A hemiacetal is produced by cyclization between Carbon 5 and carbon number ____.
1
31
When there is oxidation at the aldehyde and alcohol ends of galactose it becomes?
Mucic acid
32
When glucose gets reduced, it becomes
Sorbitol
33
How many possible stereoisomers can dihydroxyacetone have?
0
34
When starch gets hydrolyzed at its alpha 1,6 glycosidic linkage, it produces this disugar
Isomaltose
35
This desugar is used as an osmotic laxative and also in the management of portal encephalopathy
Lactulose
36
Linkages: Maltose
α 1,4 glycosidic bond
37
Linkages: Isomaltose
α 1,6 glycosidic linkage
38
Linkages: Sucrose
O-α-D-glucopyranosyl-(1,2)-β-D fructofuranoside
39
Linkages: Lactose
O-β-D-galactopyranosyl-(1,4)- β – glucopyranose
40
Linkages: Lactulose
β-(1,4) glycosidic bond
41
This desugar is used as an osmotic laxative and also in the management of portal encephalopathy
Lactulose
41
linkages: Trehalose
O- α -D-glucopyranosyl-(1,1)- α -Dglucopyranoside
42
used as a nutrient, sweetener, fermentative reagen
maltose
43
obtain from sugar cane, beet root, fruits or vegetables
Sucrose
44
- used in infant formulations, medium for peniciliin production, diluent in pharmaceuticals
Lactose
45
Which disugar can’t be reduced because both anomeric carbons are in glycosidic linkage?
Sucrose
46
A beta 1.4 glycosidic linkage is seen in
lactose
47
This homosugar is the storage form of sugar in animals and man and is used to normalize blood sugar levels when needed.
Glycogen
48
Which homosugar is classified as fructosan
Inulin
49
Glycogen and starch is classified as _____________
glucosan
50
Agar is classified as ______
galactosan
51
Which non-sulfated GAG serves as a lubricant and shock absorber in joints?
Hyaluronic acid
52
D-glucoronate + GalNac are both found in this GAG found in cartilage and joints
Chondroitin sulphate
53
The parent aldose sugar from which most aldoses come from:
GLYCERALDEHYDE
54
Mirror image, stereoisomers are called:
ENANTIOMERS
54
How many chiral carbons does the Glyceraldehyde have?
1
55
The number of possible stereoisomers fructose has:
8
56
Which simple sugar is a ketose
fructose
57
The glycosidic bond in lactose is
B-1,4
58
The sugar units in Lactose
GALACTOSE AND GLUCOSE
59
Which poly sugar is a homopolysaccharide
STARCH
60
Which polysaccharides aids in the formation of normal stool and relieves constipation?
CELLULOSE
61
This heteropolysugar is the only non sulfated GAG?
HYALURONIC ACID
62
Glucose and Galactose are epimers at ?
CARBON 4
63
From which simple sugar does starch and glycogen come from?
GLUCOSE
64
Which polysugar is built for rapid glucose storage and is released when glucose is needed?
GLYCOGEN
65
Which only sugar is an example of a GAG?
HEPARIN
66
Epimers of glucose
GALACTOSE AND MANNOSE .
67
This non-reducing sugar has no mutual rotation property
SUCROSE
68
Glucuronic acid and Acetylglucosamine are found in
HYALURONAN
69
This heterosugar is a component of bone cartilage and the cornea
CHONDROITIN SULFATE
70
When the aldehyde group of glucose gets reduced it becomes
SORBITOL
71
When fructose or mannose react with phenyl hydrazine, they form needle-like structures
osazones
72
Which of the following is a fructosan?
INULIN
73
What sugar is abundantly present in honey?
FRUCTOSE
74
. Which of these sugars has 6 carbons and ketone group as its functional group?
FRUCTOSE
75
N-Acetyl Neuramidic Acid (NANA) is
AMINO ACID SUGAR (condensation of amino sugar with Pyruvic Acid or Lactic Acid; NANA is formed from condensation of Pyruvic Acid with N-Acetyl Mannosamine)
76
Which heteroglycan sugar is an anticoagulant?
HEPARIN naturally present in mast cells;
77
Carbon Atom to which 4 different atoms are attached is called:
Chiral or Asymmetric Carbon
78
The simplest carbohydrate that has a chiral carbon.
Glyceraldehyde
79
Mirror Image
Enantiomers
80
Non – superimposable
Diastereoisomers
81
Sugars differing in configuration at only one chiral carbon are called?
Epimers
82
DHA - chiral carbon
None or 0
83
Glyceraldehyde - chiral carbon
1 Chiral Carbon
84
Glucose - chiral carbon
4
85
How many chiral carbons are there in Ribose?
3 Chiral Carbons
86
chiral carbon - . Eyrthrose
2
86
linkages : α,β – 1,2
sucrose
87
linkages : β – 1,4
Cellobiose
88
linkages: α – 1,4
Maltose
89
linkages: α,β – 1,2
Sucrose
90
linkages: Linear Polysaccharide B – 1,4
Cellulose
90
linkages: β – 1,4
Lactose
91
Sugar that has N-Acetyl-beta-D-glucosamine
chitin
92
Has Amylopectin:
Two possible answers: Dextrin or Starch
93
Main storage form of glucose in man and animals?
Glycogen
94
IdoA + GalNAc – 4s – 6s
Dermatan Sulfate
95
Sugar derivatives with antigenic determinants found in blood groups?
Glycoproteins
96
D-glucuronate + GlcNAc
Hyaluronic Acid
97
Iduronic acid + glucosamine
Heparin
98
D-Galactose + GalNAc – 6 – sulfate
Keratan Sulfate
99
Deficient enzyme for Hurler’s syndrome:
𝜶 – L – Iduronidase (GAGS affected are: Dermatan sulfate and Heparan sulfate)
100
Morquio B
B – Galactosidase
101
Sly Syndrome
B – glucoronidase
101
Morquio A
Galactosamine – 6 – sulfate