CARBOHYDRATES Flashcards

1
Q

represent a broad group of substances that include sugars, starches, gums, and celluloses.

A

Carbohydrates

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Carbohydrates contain

A

carbon, hydrogen, and oxygen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

their combustion will yield carbon dioxide plus one or more molecules of water.

A

Carbohydrates

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

formulas of many carbohydrates can be written as

A

carbon hydrates, Cn(H2O)n

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q
  • the most important carbohydrate; the major metabolic fuel of mammals (except ruminants) and are the universal fuel of the fetus.
  • It is the precursor for the synthesis of all the other carbohydrates in the body.
A

Glucose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Carbohydrates, called sugars and starches, are ____ or ____, or compounds that can be hydrolyzed to them

A

polyhydroxy aldehydes or ketones

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Sources of Carbohydrates:

A

A] sucrose [table sugar],

B] glucose,

C] fructose,

D] lactose,

E] maltose and

f] starches (found in pasta, bread, and grains). These carbohydrates can be digested by the body and provide energy for cells.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

carbohydrates that the human body doesn’t digest, including insoluble fiber,

A

A] cellulose from plants, and

B] chitin from insects and other arthropods.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

include both food sources-animal and plant products, such as fresh fruits, vegetables, corn, potatoes, milk and milk products.

A

Healthy sources of carbohydrates

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

include soda, white bread, artificial sugar, pastries, and other highly processed foods.

A

Unhealthy sources of carbohydrates

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

are an important source of fiber and other nutrients.

A

Carbohydrate foods

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

provide glucose, the main energy source for the body.

A

Sugars and starches

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Major sources of Healthy Carbohydrates

A

Good Carbs:
Vegetables: All of them. …
Whole fruits: Apples, bananas, strawberries, etc.
Legumes: Lentils, kidney beans, peas, etc.
Nuts: Almonds, walnuts, hazelnuts, macadamia nuts, peanuts, etc.
Seeds: Chia seeds, pumpkin seeds.
Whole grains: Choose grains that are truly whole, as in pure oats, quinoa, brown rice, etc.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

six major functions in the body of carbohydrates

A

-providing energy,

-regulating blood glucose,

-sparing the use of proteins for energy,

-breaking down fatty acids,

-providing dietary fiber and

-natural sweetener for foods.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Stored glucose energy, with the majority of it in the muscle and liver

A

glycogen

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Primary Function of Carbohydrates.

A

-supply energy to all cells in the body

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

called Carbs, are defined as aldehydic or ketonic compounds with some number of oxydrilic groups (so polyhydroxy aldehydes or ketones as well).

A

Carbohydrates

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

three major classes of carbohydrates

A

monosaccharides, oligosaccharides, and polysaccharides.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q
  • or simply sugars are formed by only one polyhydroxy aldehydic or ketonic unit.
  • the most abundant monosaccharide is D-glucose, also called dextrose.
  • the simplest carbohydrates,
    generally have 3 to 6 C atoms in a chain with an
    aldehyde or ketone ending and many –OH groups.
A

Monosaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

most abundant monosaccharide is D-glucose, also called

A

dextrose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

formed by short chains of monosaccharide units (from 2 to 20) linked one to the next by chemical bonds, called glycosidic bonds.

A

Oligosaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q
  • The most abundant oligosaccharides
  • formed by two monosaccharides, and especially in the human diet the most important are sucrose (common table sugar), lactose, and maltose.
A

disaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

polymers consisting of 20 to 107 monosaccharide units; they differ each other for the monosaccharides recurring in the structure, for the length and the degree of branching of chains or for the type of links between units.

A

Polysaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

Polysaccharides if they contain only one type of monosaccharide as starch, glycogen, and chitin;

A

Homopolysaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
Polysaccharides, instead, contain two or more different kinds (e.g. hyaluronic acid).
heteropolysaccharides
26
derives from the Greek word “sakcharon”, which means sugar.
saccharide
27
Aldehyde monosaccharides
aldoses
28
ketone monosaccharides
ketoses.
29
The simplest aldose
glyceraldehyde.
30
simplest ketose
dihydroxyacetone
31
They are constitutional isomers of each other, sharing the formula C3H6O3.
glyceraldehyde and dihydroxyacetone.
32
monosaccharide that have 3 C’s
triose
33
monosaccharide that have 5 C’s
pentose
34
monosaccharide that have 4 C’s
tetrose
35
monosaccharide that have 6 C’s.
hexose
36
-sweet tasting, but their relative sweetness varies greatly. -They are polar compounds with high melting points. -The presence of so many polar functional groups capable of hydrogen bonding makes the monosaccharides very water soluble
Monosaccharides
37
blood sugar and the most abundant monosaccharide
Glucose
38
Normal blood glucose levels
70-110 mg/dL
39
Excess glucose is stored as
polysaccharide glycogen or as fat.
40
regulates blood glucose levels by stimulating the uptake of glucose into tissues or the formation of glycogen.
Insulin
41
one of the components of the disaccharide lactose
Galactose
42
lack an enzyme needed to metabolize galactose, which accumulates and causes cataracts and cirrhosis.
Patients with galactosemia
43
- one of the components of the disaccharide sucrose. - It is a ketohexose found in honey and almost twice as sweet as table sugar with the same number of calories per gram.
Fructose
44
- are composed of two mono- saccharides. - They link together by forming an acetal
Disaccharides
45
- When this reaction occurs between two mono- saccharides, the bond that joins them together is called a____ - joining the two rings can be alpha ( or beta (
glycosidic linkage.
46
If the bond is alpha ()
glycoside bond is down ex.1 -> 4 a-glycosidic linkage
47
If the bond is beta ().
glycoside bond is up ex.1 -> 4 B-glycosidic linkage
48
cleaves the C—O glycosidic linkage and forms two monosaccharides.
Hydrolysis
49
the disaccharide in milk; it consists of 1 galactose ring and 1 glucose ring joined by a 1->4-B-glycosidic bond.
Lactose
50
The disaccharide bond is cleaved by the enzyme
lactase
51
Individuals who are lactose intolerant no longer produce this enzyme.
lactase
52
True or false Without the enzyme, lactose cannot be digested, causing abdominal cramps and diarrhea.
True
53
- a disaccharide consisting of 1 glucose ring and 1 fructose ring. - very sweet, but contains many calories. *To reduce caloric intake, many artificial sweeteners have been developed.
Sucrose (table sugar)
54
(sold as Equal) is hydrolyzed into phenylalanine, which cannot be processed by those individuals with the condition phenylketonuria. 16
Aspartame
55
(sold at Sweet’n Low) was used extensively during World War I.
Saccharine
56
(sold as Splenda) has a very similar structure to sucrose.
Sucralose
57
contain three or more mono- saccharides joined together.
Polysaccharides
58
- an unbranched polymer made up of repeating glucose units joined by 14-- glycosidic linkages - found in the cell walls of all plants, where it gives support and rigidity to wood, plant stems, and grass. - makes up the insoluble fiber in our diets, which is important in adding bulk to waste to help eliminate it more easily.
Cellulose
59
Enzyme used to hydrolyze cellulose and cannot me possessed and digested by humans
B-glycosidase
60
- polymer made up of repeating glucose units joined by alpha glycosodic linkages. - present in corn, rice, wheat, and potatoes.
starch
61
- The first main type of starch - an unbranched polymer linked by 14--glycosidic linkages
amylose
62
- second type of starch, which is the branched form of starch - a branched polymer linked by 14- and 16--glycosidic linkages
amylopectin
63
Both starch molecules amylopectin and amylose can be digested by humans using the enzyme __________.
amylase
64
-the major form of polysaccharide storage in animals, similar in structure to amylopectin. -It is stored mainly in the liver and in muscle cells -when glucose is needed for energy, glucose units are hydrolyzed from its ends -many ends are available for hydrolysis
Glycogen
65
- are a group of unbranched carbohydrates derived from alternating amino sugar and glucuronate units.
Glycosaminoglycans (GAGs)
66
a Glycosaminoglycans and component of cartilage and tendons.
chondroitin
67
a Glycosaminoglycans, an extracellular fluids that lubricate joints and in the vitreous humor of the eye.
hyaluronate
68
stored in the mast cells of the liver, helps prevent blood clotting.
Heparin
69
a polysaccharide formed from N-acetyl-D-glucosamine units joined together by 1->4-B-glycosidic linkages. 10
Chitin
70
four blood types
A, B, AB, and O.
71
based on 3 or 4 monosaccharides attached to a membrane protein of red blood cells. *Each blood type has the monosaccharides below: 11
Blood type
72
blood type that contains a fourth monosaccharide
Type A
73
blood type that contains an additional D-galactose unit.
Type B
74
blood type that has both type A and type B carbohydrates.
Type AB
75
called universal donors, because people with any other blood type have no antibodies to type O
type O blood
76
are universal recipients because their blood contains no antibodies to A, B, or O. 15
type AB blood
77
- a convention for drawing molecules and quickly designating stereochemistry without laboriously trying to use wedges and hashes to specify the 3-D relationships - The definition is that every carbon is specified completely by a cross designating the carbon (at the center) and the four bonds to that carbon
Fischer projection
78
an early carbohydrate chemist, developed it so that it could continue to be used correctly and consistently even after experimental proof of configuration was developed.
Emil Fischer
79
All carbohydrates have 1 or more chirality centers
Fischer Projection Formula in monosaccharides
80
The prefix D is used when the –OH group is drawn on the right side of the carbon chain. The prefix L is used when the –OH group is drawn on the left side of the carbon chain.
Fischer Projection Formula in monosaccharides
81
Monosaccharides With More than One Chirality Center
Glucose - 4 chirality centers
82
True or false The configuration of the chirality center farthest from the carbonyl group determines whether a monosaccharide is D or L.
true
83
All naturally occurring sugars are D sugars
Monosaccharides With More than One Chirality Center
84
When an aldehyde reacts with an alcohol, a _______ is formed
hemiacetal
85
was developed and used by Emil Fischer to identify sugars may be classified as reducing or non-reducing based on their reactivity with Tollens', Benedict's, or Fehling's reagents.
osazone reaction
86
f a sugar is oxidized by these reagents it is called
reducing sugar
87
commonly used to detect aldehyde functional group.
Tollens' test
88
When the aldehyde function of an aldose is oxidized to a carboxylic acid the product is called an
aldonic acid
89
If both ends of an aldose chain are oxidized to carboxylic acids the product is called an
aldaric acid
90
The aldehyde group is easily oxidized to a carboxylic acid using
Benedict’s reagent. *Aldoses can be oxized, while ketones cannot. 3
91
Can aldoses be oxized
yes
92
can ketones be oxized
no
93
makes up the insoluble fiber in our diets, which is important in adding bulk to waste to help eliminate it more easily.
Cellulose
94
the primary source of glucose in our food.
Starch
95
the main sugar that is utilized by the cell to produce ATP (Adenosine triphosphate).
glucose