Carbohydrates Flashcards

1
Q

Functions of carbohydrates

A

Energy source (eg. glucose)
Store of energy (eg. starch and glycogen)
Structural units (eg. cellulose in plants and chitin in insects)

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2
Q

Glycosidic bond

A

A bond formed by two monosaccharides via condensation reaction

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3
Q

Monosaccharides

A

Have a backbone of single bonded carbon atoms, with one double bonded with oxygen to form a carbonyl group

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4
Q

General formula of a monosaccharide

A

(CH2O)n ->where n is a number between 3 and 7

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5
Q

Draw the structure of a beta glucose

A
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6
Q

Draw the structure of a alpha glucose molecule

A
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7
Q

Draw the structure of ribose

A
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8
Q

Draw the structure of deoxyribose

A
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9
Q

Hexose sugars

A

Alpha and beta glucose
have 6 carbon atoms

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10
Q

Pentose sugars

A

ribose and deoxyribose
have 5 carbon atoms

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11
Q

Maltose equation

A

α-glucose + α-glucose

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12
Q

Sucrose equation

A

α-glucose + fructose

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13
Q

Lactose equation

A

α-glucose + β-galactose

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14
Q

Cellobiose equation

A

β-glucose + β-glucose

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15
Q

What happens when the α/β-glucose joins to form disaccharides

A

A condensation reaction occurs to form a glycosidic bond. 2 hydroxyl (-OH) groups line up next to each other and a water molecule is removed, leaving an oxygen atom as a link

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16
Q

How are disaccharides broken into monosaccharides

A

Hydrolysis
Water provides a hydroxyl group (-OH) and hydrogen group (H), helping glycosidic bonds to break

17
Q

Homopolysaccharides

A

Polysaccharides made solely of one type of monosaccharide (eg strach)

18
Q

Heteropolysaccharide

A

Polysaccharides made up of more than one type of monomer (eg hyaluronic acid)

19
Q

Where do plants store energy

A

starch in chloroplasts and membrane bound starch grains

20
Q

where do humans store energy

A

glycogen in liver and muscle cells

21
Q

Why does starch and glycogen act as good stores of monosaccharides

A

-> compact- don’t occupy a large amount of space and are dense
-> hold glucose molecules in chains which can easily be ‘snipped off,’ by hydrolysis for respiration
-> branched (amylose)/unbranched (amylopectin and glycogen) chains- branched chains are more compact so many glucose molecules can be snipped off by hydrolysis when lots of energy is required quickly

22
Q

Structure of Amylose (plants)

long chain of α-glucose molecules with 1,4 glycosidic bonds

A

coils into spiral shape, held in shape by Hydrogen bonds
Hydroxyl groups are placed inside coil, making molecule less soluble

23
Q

Structure of amylopectin (plants)

Glycosidic bonds between carbons 1-4 and additional branches of 1-6 bonds -> alpha glucose

A

Coils into spiral shape held together by hydrogen bonds
Has branches emerging from spiral

24
Q

Structure of Glycogen (animals)

Glycosidic bonds between carbons 1-4, branches formed by 1-6 bonds -> alpha glucose

A

1-4 bonded chain is smaller than amylopectin
less tendency to coil
more branches, more compact
easier to remove monomer units

25
Cellulose
Tough, insoluble, fibrous substance homopolysaccharide made up of long chains of β-glucose molecules, bonded through condensation to form glycosidic bonds
26
Structure of cellulose
27
How are cell walls formed
60-70 cellulose chains bind to form microfibils, which bundle to form macrofibils with up to 400 microfibils- these are embedded in pectins to form cell walls
28
Why are β-glucose molecules flipped 180 degrees in cellulose chains
To prevent the chains from spiralling allow formation of hydrogen bonds which improves strength and stability
29
Benefits of cellulose for cell walls
-> Macrofibils + microfibils have high tensile strength due to (H) bonds between chains +strong glycosidic bonds -> macrofibils run in all directions, criss-crossing for extra strength -> Glycosidic bonds are less easy to break -> space between macrofibils for water and mineral ions to pass through cell makes cell wall fully permeable
30
Cell wall functions
-> High tensile strength prevents plant cells from bursting when turgid, protecting the cell membrane -> Macrofibil structure can be reinforced for extra support/to make the walls waterproof