Carb Flashcards
What are non sugars
Polysaccharides
General formula for monosaccharide
Cn H2n On
Glucose is
Aldohexose
Fructose is
Ketohexose
Simplest monosaccharide
Triose
Dihydroxyacetone
Glyceraldehyde
Monosaccharide without chiral carbon
Dihydroxyacetone
What are enantiomers
Non superimposeable images
L and D (hydroxy group) (next to last carbon)
Epimers
Differs only at one position (but not anomeric carbon)
Eg Glu and mannose - C2
Glu and galactose- C4
Hemiacetal and hemiketals
Hemiacetals- aldehyde react w alc
Hemiketal- ketone react w alc
Anomeric carbon
Position of hydroxyl group
Belo- alpha
Above- beta
Equilibrium mixture of glu, mutarotation
37% alpha- +112
63% beta - +19
Results - +52.7
Carbs have n glycosidic or o glycosidic
O glycosidic
Hydrolysis of sucrose
Sucrose- dextrarotatory +66.5
D glu. +52.7
D fructose- -92
Result levorotatory
Therefore hydrolysis of sucrose is known as inversion
What is invert sugar
Equimolar mixture of
Glu
Fructose
What are reducing sugars and exp
That have free anomeric carbon
Can react w oxidising agent- ferric/cupric
Exp- sucrose, trehalose