Carb Flashcards

1
Q

What are non sugars

A

Polysaccharides

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

General formula for monosaccharide

A

Cn H2n On

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

Glucose is

A

Aldohexose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Fructose is

A

Ketohexose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Simplest monosaccharide

A

Triose
Dihydroxyacetone
Glyceraldehyde

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Monosaccharide without chiral carbon

A

Dihydroxyacetone

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What are enantiomers

A

Non superimposeable images
L and D (hydroxy group) (next to last carbon)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

Epimers

A

Differs only at one position (but not anomeric carbon)
Eg Glu and mannose - C2
Glu and galactose- C4

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

Hemiacetal and hemiketals

A

Hemiacetals- aldehyde react w alc
Hemiketal- ketone react w alc

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Anomeric carbon

A

Position of hydroxyl group
Belo- alpha
Above- beta

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Equilibrium mixture of glu, mutarotation

A

37% alpha- +112
63% beta - +19

Results - +52.7

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Carbs have n glycosidic or o glycosidic

A

O glycosidic

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Hydrolysis of sucrose

A

Sucrose- dextrarotatory +66.5
D glu. +52.7
D fructose- -92

Result levorotatory
Therefore hydrolysis of sucrose is known as inversion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

What is invert sugar

A

Equimolar mixture of
Glu
Fructose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

What are reducing sugars and exp

A

That have free anomeric carbon
Can react w oxidising agent- ferric/cupric
Exp- sucrose, trehalose

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Test for starch

A

Iodine