Calculting pH Of Weak Acids Flashcards

1
Q

What is the strength of an acid

A

The extent of ionisation

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2
Q

What is the concentration of an acid

A

The amount in moles of acid in a cubic decimetre

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3
Q

What is the acid dissociation constant (Ka)

A

The equilibrium constant(acid dissociation constant) for the ionisation of a weak acid

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4
Q

Ka general equation

A

[H+(aq)][A-(aq)]/[HA(aq)] With A- is the ion produced when the acid ionises

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5
Q

What does a higher Ka mean

A

More likely it is to dissociate so stronger acid

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6
Q

What is pKa

A

Log of acid constant, pKa=pH

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7
Q

How to get pKa from ka

A

PKa= -logKa

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8
Q

How to get ka from pka

A

ka= 10^-pka

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9
Q

Two assumptions made when using ka

A

-[H+]=[A-], in equation all H+ coming from the dissociation of acid but also dissociation of water so [H+]>[A-] due to water contributing to [H+]
-[HA]start= [HA]equilibrium, second is that concentration of acid doesn’t change as equilibrium lies so far to the left it can be considered equal as only tiny amount of HA dissociates

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10
Q

Process of working out pH of weak acid from its concentration and ka

A

ka= [H+]^2/[HA]
[H+]= square root of ka[HA]
Then -log[H+]

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