Calculting pH Of Weak Acids Flashcards
What is the strength of an acid
The extent of ionisation
What is the concentration of an acid
The amount in moles of acid in a cubic decimetre
What is the acid dissociation constant (Ka)
The equilibrium constant(acid dissociation constant) for the ionisation of a weak acid
Ka general equation
[H+(aq)][A-(aq)]/[HA(aq)] With A- is the ion produced when the acid ionises
What does a higher Ka mean
More likely it is to dissociate so stronger acid
What is pKa
Log of acid constant, pKa=pH
How to get pKa from ka
PKa= -logKa
How to get ka from pka
ka= 10^-pka
Two assumptions made when using ka
-[H+]=[A-], in equation all H+ coming from the dissociation of acid but also dissociation of water so [H+]>[A-] due to water contributing to [H+]
-[HA]start= [HA]equilibrium, second is that concentration of acid doesn’t change as equilibrium lies so far to the left it can be considered equal as only tiny amount of HA dissociates
Process of working out pH of weak acid from its concentration and ka
ka= [H+]^2/[HA]
[H+]= square root of ka[HA]
Then -log[H+]