C8-Reaction Kinetics Flashcards
Based on collision theory, what conditions must particles fulfil for a reaction to occur?
- Particles collide with each other
- Collisions in correct orientation
- Collisions achieve activation energy
Rate of reaction
Change in quantity of reactants or products per unit time.
Activation energy
Minimum amount of energy that reacting particles must achieve to overcome it for a chemical reaction to occur.
Where’s Ea on energy profile diagram?
From reactants to peak
What’s Ea usually for?
- Break bonds in reacting particles.
- Overcome repulsive forces when reacting particles close to each other (so that they can collide)
Why are transition metals good catalyst?
- Have partially filled d electron orbitals.
- Enable transition metal to form temporary bonds with reacting particles.
- Weak adsorption of transition metal enable it to remain chemically unchanged at the end of reaction.
Autocatalysis
A condition when a product of a chemical reaction acts as a catalyst.
Homogenous catalyst
Catalyst and reactants have same physical state
Heterogenous catalyst
Catalyst and reactants have different physical states
When will a system achieve kinetic stability?
When the reaction has high activation energy that no reacting particles and no collision achieve enough energy to react.