C8: Rates Of Reaction Flashcards
List the factors which affect rates of chemical reactions
- Pressure
- Surface Area
- Heat
- Concentration
- Catalyst
What is collision theory?
Chemical reactions can occur only when reacting particles collide with each other and with sufficient energy
What is the activation energy?
the minimum amount of energy that particles must have to react
Why does increasing the temperature increase the rate of reaction?
Increasing the temperature increases the frequency of collisions and makes the collisions more energetic, and so increases the rate of reaction.
What is a catalyst?
Catalysts are substances that speed up chemical reactions without being changed or used up during the reaction.
How do catalysts increase the rate of reaction?
- Catalysts decrease the actuvation energy; this
increases the proportion of particles with energy to react. - Catalysts provide a alternate pathway for a chemical reaction that has a lower activation energy.
What is the effect of changing concentration?
An increase in concentration increases the rate of reaction due to a greater number of collisions between reacting particles.
How do you calculate the rate of reaction?
Quantity of reactant used/ time
Or
Quantity of product formed/ time
What are the units for rate if reaction?
Grams/s pr cm^3/s
What is the method for measuring gas volume?
The gradient of this graph will be equal to the reaction rate. The steeper the graph the faster the reaction.
Method 1: Conical flask, gas syringe and cork
Method 2: Conical flask, delivery tube, cork, trough with water and an inverted measuring cylinder
What is the method of measuring mass loss?
Place the conical flask with the mixture and cotton on a weighing scale and measure it. As the reaction proceeds, measure the volume of gas lost.
What is a different way of measuring rate of reaction and what equipment is used?
Time for a solution to become opaque or coloured:
Conical flask, dilute acid added to a transparent solution and a cross beneath the flask. Wait for the cross beneath the flask to not be visible and time how long this takes.
How do you calculate the mean rate of reaction?
Change in volume / change in time
How do you find the rate of reaction at a specific time?
Using the gradient of the curve at the time. Find the gradient using:
The difference in y (vertical) / difference in x (horizontal). The tangent’s hypotenus must only touch the singular point.
Explain the reuslts that may be obtained at different temperatures using particle theory
The result of a higher temperature shows a steeper gradient as due to an increase of heat, particles have more kinetic enegry, resulting in a higher frequency of collisions as collisions have more energy resulting in more passing the activation energy, speeding up the rate of reaction. Furthermore, the result of the higher temperature finishes earlier as the reaction is much quicker however an equal volume of gas is released as there are equal volumes of magnesium.