C8: Rates and equilibrium 1 Flashcards
what is the rate of a reaction
how quickly reactants are used up or products are produced
what is the equation for calculating the mean rate of reaction
mean rate = change in quantity of product or reactant/time taken
what is the unit for rate of reaction in a reaction involving a change in mass
g/s
what is the unit for rate of reaction in a reaction involving a change in volume
cm/s
what is the activation energy
the minimum amount of energy colliding particles have to have before a reaction will take place
what effect does increasing concentration have on the rate of reaction
increases
why does increasing the concentration have this effect
more reactant particles in the same volume lead to more frequent collisions
what does the effect of increasing the pressure have on the rate of reaction
increases
why does increasing the pressure cause this effect
less space between particles means more frequent collisions
what effect does increasing the surface area have on the rate of reaction
increases
why does increasing surface area have on the rate of reaction
more reactant particles are exposed and able to collide leading to more frequent collisions
what effect does increasing temperature have on the rate of reaction
increases
why does increasing temperature have this effect
particles move faster, leading to more frequent collision - particles have the same activation energy, so more collisions result in a reaction
what is a catalyst
a substance that increases the rate of a reaction but is not used up in the reaction
how do catalysts increase the rate of reaction
lower the activation energy of the reaction, so more collisions result in a reaction
what is a reversible reaction
the reactants turn into products and the products turn into reactants
which symbol shows a reversible reaction
⇌
what is dynamic equilibrium
the point in a reversible reaction when the rate of the forward and reverse reactions are the same
what are the three reaction conditions that can be changed
concentration, temperature, pressure
what is Le Chatelier’s principle
the position of equilibrium will shift to oppose external changes
what is the effect of increasing the concentration of reactants on a reaction at dynamic equilibrium
favours the forward reaction
what is the effect of decreasing the concentration of products on a reaction at dynamic equilibrium
favours the forward reaction
what is the effect of increasing pressure on a reaction at dynamic equilibrium
favours the reaction with the fewest molecules
what is the effect of decreasing pressure on a reaction at dynamic equilibrium
favours the reaction that leads to the most molecules
what is the effect of increasing temperature on a reaction at dynamic equilibrium
favours the endothermic reaction
what is the effect of decreasing temperature on a reaction at dynamic equilibrium
favours the exothermic reaction