C8 - Chemical Analysis Flashcards

1
Q

what is a pure substance

A

a single element or compound not mixed with any other substance

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2
Q

what can be used to distinguish pure substances from mixtures

A

melting and boiling point data

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3
Q

what is a formulation

A

a mixture that has been designed as a useful product

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4
Q

how are formulations made

A

mixing the components in carefully measured quantities to ensure the product has the required properties

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5
Q

give examples of formulations

A

fuels
cleaning agents
paints
medicines
alloys
fertilisers
food

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6
Q

formula to calculate rF value

A

distance moved by substance/ distance moved by solvent

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7
Q

what may affect the rF value

A

the solvent

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7
Q

what is the test for hydrogen

A

using a burning splint held at the open end of a test tube of gas. hydrogen makes a pop sound and burns

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7
Q

how can a chromotogram be used to identify substances by comparing them with known substances

A

the number of spots they produce and the colour
how far the spots have moved up the paper or have the same Rf value

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8
Q

oxygen test

A

using a glowing splint inserted into a test tube of the gas. the splint relights in oxygen

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9
Q

carbon dioxide test

A

using an aqueous solution calcium hydroxide. carbon dioxide when shakened or bubbled through will turn the limewater milky

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10
Q

chlorine test

A

if damp litmus paper is put onto chlorine gas it is bleached

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11
Q

what can flame tests be used to identify

A

some metal ions

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12
Q

what colour do lithium compounds turn in the flame test

A

crimson flame

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13
Q

what colour do sodium compounds turn in the flame test

A

yellow flame

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14
Q

what colour do potassium compounds turn in the flame test

A

lilac flame

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15
Q

what colour do calcium compounds turn in the flame test

A

an orange-red flame

16
Q

what colour do copper compounds turn in the flame test

A

green flame

17
Q

what can be done if a sample contains a mixture of ions

A

some flame colours can be masked

18
Q

what can sodium hydroxide solution be used to identify

A

some metal ions

19
Q

which ions form white precipitates when added to sodium hydroxide

A

aluminium (but then redissolves in excess NaOH to form a colourless solution), calcium and magnesium ions

20
Q

what ions form coloured precipitates when added to sodium hydroxide

A

copper ii, iron ii, iron iii

21
Q

what colour does copper ii form when added to sodium hydroxide

A

blue precipitate

22
Q

what colour do iron ii ions form when added to sodium hydroxide

A

green precipitate

23
what colour do iron iii ions form when added to sodium hydroxide
brown precipitate
24
balanced equation to represent calcium reacting with insoluble hydroxide
Ca2+ + 2OH- ------> Ca(OH)2
25
balanced equation to represent copper ii reacting with insoluble hydroxides
Cu2+ + 2OH- ----> 20
26
balanced equation to represent iron ii reacting with insoluble hydroxides
Fe2+ + 2OH- ---> Fe(OH)2
27
balanced equation to represent iron iii reacting with insoluble hydroxides
Fe3+ + 3OH- ------> Fe(OH)3
28
balanced equation to represent alumminium reacting with insoluble hydroxides
Al3+ + 3OH- ---> Al(OH)3
29
balanced equation to represent magnesium reacting with insoluble hydroxides
Mg2+ + 2OH- ---> Mg(OH)2
30
what do carbonates to react with to form carbon dioxide gas
dilute acids
31
what can CO2 be identified with
limewater
32
what do halide ions produce and when
precipitates with silver nitrate when there is dilute nitirc acid
33
what colour precipitate is silver chloride
white
34
what colour precipitate is silver bromide
cream
35
what colour is silver iodide
yellow
36
what do sulfate ions produce
white precipitate with barium chloride solution in the presence of hydrochloric acid
37
what can be detected using instrumental methods
elements and compounds
38
benefits of instrumental methods
accurate sensitive rapid can be used to identify ions in mixtures
39
how does flame emission spectroscopy work
the sample is put into a flame and the light given out is passed through a spectroscope. the output is a line spectrum that can be analysed to identify the metal ions in the solution and measure their concentrations