C6.2 (2) Flashcards
define a polymer
large molecules built up from small units (or monomers)
how does addition polymerisation work?
in terms of bonds
- C=C double bond in alkenes is removed to produce a C-C single bond
- the bonds then join with unsaturated molecules to form a long saturated polymer
how do you produce an addition polymerisation reaction?
react alkenes together at high pressure and a catalyst
what is special about addition polymerisation reactions compared to condensation polymerisation?
- addition polymerisation only produces one product
how would you generally represent the product of an addition polymerisation reaction?
as a repeating unit (so the alkane , with two lines sticking out of the bracket), and a small n
- REMEMBER ALKANE NLY HAS ONE LINE BETWEEN THEM AS BONDS HAVE OPENED UP *
what does the polymer name depend on?
eg. if propene is monomer, what is the polymer name?
depends on the name of the monomer
- propene becomes poly(propene)
- MONOMER NAME REMAINS SAME, BUT BOND DIAGRAM DOES NOT*
what is an addition polymerisation reaction?
when (only 1 type of) small monomers (alkenes) join together to form one large polymer (saturated hydrocarbon chain)
what is a condensation reaction?
two molecules reacting together to produce one large molecule and a water molecule
how many functional groups must there be within a monomer for it to react? (during a condensation reaction)
- at least 2
how many monomers does each polymer (produced by a condensation reaction) usually contain?
100s or 1000s of monomers
what functional groups react together to produce a polyester?
(and how many of each one)
2 -OH groups (from alcohols) - HYDROXYL group
2 -COOH groups (from carboxylic acids) - CARBOXYL group
what are the produced when a polyester is formed?
- an ester group ‘‘-COO-“
- water
what functional groups react together to produce a polyamide? - and how many of each one ,k
(and what makes up an amide group)
2 carboxyl groups (-COOH)
2 animo groups (-NH2)
-CONH
what is a real life example of a polyamide?
a protein
explain how water is produced when a polyester is made
- OH lost off COOH group
- H lost of OH group
- CO and O join together to make a polyester
- OH and H lost join to form water
how do you represent a polymer after a condensation reaction?
draw repeating units with block diagrams (each block would represent a hydrocarbon group)
mainly draw repeating unit + n at the bottom
what 3 factors are needed to carry out a condensation reaction?
- high pressure
- high temperature
- with a catalyst
how would you produce a polyester in a school lab?
- heat together an alcohol + carboxylic acid
in presence of an acid catalyst
uses of polyesters?
clothing/fizzy drink bottles
ie. a polyester named PET
uses of polyamides?
clothing/ carpets
ie. polyamide named nylon
what is DNA?
a polymer made from four different monomers (called nucleotides)
what does a nucleotide (in DNA) consist of?
- a phosphate group (circle)
- deoxyribose sugar (pentagon)
- an organic base (rectangle)