C6- The Rate And Extent Of Chemical Changes Flashcards
Rate of chemical reaction
How fast the reactants are changed into products
Graphs for rate of reaction
Steeper the line the faster the rate of reaction, over the time the line becomes become less steep as reactants are used up
Collision theory
The more collisions the faster rhe reaction. The energy transferred during a collision. Particled have to collide with enough energy for the collision to be successful
Factors affecting rate of reaction
Temperature, surface area, conentration of a solution, presence of a catalyst
Rate of equation equation
Amount of reactant used or of product formed/time
Three ways to measure rate of reaction
Precipitation and colour change, change in mass, the volume of gas given off
Precipitation and colour change rp
- Record visual chnage in a reaction if initial solution is transparent and the product is a precipitate which clouds the solution
- Observe a mark through the solution and measure how long it takes for it to dissappear - the faster the mark dissapears, the quicker the reaction
- If reactants are coloured and the products are colourless time how long it takes for solution to lose or gain its colour
- Cant plot graph and results are subjective
Change in mass rp
- Measuring speed of a reaction that produces a gas can be carried out using a mass balance
- As gas is released disappearing mass is measured
- Quicker reading drop, faster the reaction
- Take measurement at regular intervals to plot graph
The volume of gas given off rp
- Use gas syringe to measure the volume of gas given off
- The more gas given off during time interval the faster the reaction
- Can make graph when measure at regular time intervals, if reaction too vigoroud the plunger can be blown out
Two rates experiment- magnesium and HCl react to produce H2 gas
- Add set volume of dilute hydrochrloric acid to conical flask and carefully place on balance
- Add magnesium ribbon to acid and quickly plug the flask with cotton wool
- Start stopwatch and record the mass on balance tak reading of mass at regular intervals
- Plot results and repeat with more concentrated acid soltion with other variables staying the same
- Three graphs show that a higher concentration of acid gives a faster rate of reaction
Two rates experiment - sodium thiosulfate and HCl produce a cloudy precipate
- Two chemicals both clear and they react together to form a yellow precipitate
- Start by adding a set volume of dilute solution thiosulfate to conical flask
- Place flask on piece of paper with black cross drawn on it and add dilute HCl to flask start stopwatch
- Watch black cross dissappear through the cloudy sulfur and time it takes
- Results show effect of increasing concentration of HCl on rate of reaction, higher concentration quicker the reactiom
Reversible reactions
Products react to form their reactants
Reversible reactions can be exothermic and endothermic
If reaction is endothermic in one direction, it will be exothermic in the other
Le chateliers principle
Idea that if you change the conditions of a reversible reaction at equlibrium the system will try to counteract that change
Things that effect position of equlibrium
Temperature, pressure, the concentration of the reactants and products