C6 Chemistry out there Flashcards
What is electrolysis?
Electrolysis is the decomposition of liquid by passing electricity through it. (Flow of charge by moving ions and the discharge of ions at the electrodes)
What is the anode?
What is the cathode?
- Positive electrode
- Negative electrode
What are cations?
What are anions?
- Positively charged (Loss of electrons)
- Negatively charged (Gain of electrons)
Describe what the term electrolyte means?
Electrolyte is the liquid which conducts the electricity and is decomposed or broken down during electrolysis
What apparatus is required for electrolysis?
- DC power supply
- Anode
- Cathode
Where are the negative ions and positive ions discharged?
Cathode (Positive ions)
Anode (Negative ions)
Describe the chemical test for oxygen and hydrogen
- When hydrogen burns with a lit splint, it makes a ‘pop’ sound
- Oxygen relights a ‘glowing’ splint
Describe the observations of the electrolysis of Copper(II) Sulfate solution using carbon electrodes
- The cathode gets plated with copper and bubbles are formed at the anode
- The blue colour will slowly disappear
- Oxygen is produced at the anode
What factors affect the amount of substance produced during electrolysis?
- Time
- Current
Name the products made during the electrolysis of NaOH
Oxygen - anode
Hydrogen - cathode
Name the products made during the electrolysis of H2SO4
Hydrogen - Cathode
Oxygen - Anode
Why does the electrolysis of NaOH produce Hydrogen instead of Sodium at the Cathode
Because Na is higher in the reactivity series, hence Hydrogen is discharged as a preference
Explain why an ionic solid can not be electrolysed but the molten liquid can be electrolysed
The ions in the ionic solid can not move as they vibrate in a fixed position, the ions in a molten liquid can move, hence then can be electrolysed
What type of reaction occurs between hydrogen and oxygen?
Exothermic (energy is released into the atmosphere)
Describe what a fuel cell is
A fuel cell is a cell supplied with fuel and oxygen that uses the energy released from the reaction between the fuel and oxygen to produce electrical energy efficiently
What fuel is used in a hydrogen-oxygen fuel cell?
Hydrogen
Why does a hydrogen-oxygen fuel cell not form a polluting waste product?
Unsure
Balanced symbol equation for the reaction between hydrogen and oxygen
2H2 +O2 —-> 2H2O
Energy-level diagram
2H2 + O2 ——–> 2H2O
Energy
Released
Construct the balanced symbol equation for the overall reaction in a hydrogen-oxygen fuel cell
Equation
Advantages of fuel cells
- Provides water for astronauts
- Lightweight
- Compact
- No moving parts
Disadvantages of using fuel cells
- Fuels cells often contain harmful catalysts that have to be disposed at the end of the lifetime of a fuel cell
- Production of the hydrogen and oxygen will involve the use of energy which may have to come from the burning of fossil fuels
Explain why the car industry is developing fuel cells
- No carbon emissions from the car
- Fossil fuels currently used are non-renewable
- Large source of hydrogen is available by decomposing water
What is oxidation and reduction?
- Oxidation is the addition of oxygen
- Reduction is the removal of oxygen
What two conditions are required for rusting of steel and iron?
- Water
- Oxygen
Methods to prevent rusting
- oil and grease
- paint
- galvanising
- sacrificial protection
- alloying
- tin plating
How do these methods prevent rusting?
- they prevent oxygen and water reaching the surface of the metal requiring protection
Order of reactivity (most to least)
Magnesium
Zinc
Iron
Tin
Temperature change during a displacement reaction
Temperature increases because it is an exothermic reaction
Define the terms :
- oxidation and reduction
- oxidising agent and reducing agent
Oxidation is the loss of electrons
Oxidising agent is a substance that can remove electrons from other substances, oxidising them
Reduction is the gain of electrons
Reducing agent is a substance that can give electrons to other substances, reducing them
Why is rusting a redox reaction?
- Iron loses electrons
- Oxygen gains electrons
How does sacrificial protection work and protect the iron underneath it?
- Use of metal such as zinc or magnesium
- Use of metal which is more reactive than iron
- Sacrificial metal will lose electrons in preference to the underlying iron
Explain the disadvantage of using tin plating to protect the iron
- Tin acts as a barrier stopping water or oxygen reaching the surface of the iron
- When the tin layer is scratched, the iron will lose electrons in preference to the tin as it is more reactive than tin and so the iron rust even more quicker than on its own
Rusting word equation
Oxygen + Water + Iron —-> Hydrated iron (III) Oxide
Explain how galvanising protects iron from rusting
- Galvanised iron is coated with zinc
- Layer of zinc stops water and oxygen from reaching the surface of the iron
- Zinc also acts as a sacrificial metal
Explain displacement reactions in terms of oxidation and reduction
- Metal ion is reduced by gaining electrons
- Metal atom is oxidised by losing electrons
Explain why alcohols aren’t hydrocarbons
Because they contain atoms other than hydrogen and carbon
What are the required conditions for fermentation?
- 25 to 50 degrees Celsius
- Presence of water
- Yeast