C6 Flashcards
Why is it called a redox reaction?
Because reduction and oxidation happens at the same time
What is reduction?
Gain of electrons
What is oxidation?
Loss of electrons
What is an oxidising agent?
One that accepts electrons and gets reduced
What is a reducing agent?
It donates electrons and gets oxidised
Give an example of a redox reaction
Iron atoms are oxidised to iron(11) ions when they react with dilute acid
Iron atoms lose electrons - they’re oxidised by the hydrogen ions
Hydrogen ions gain atoms they are reduced by the iron atoms
What are displacement reactions?
Redox reactions
What does a displacement reaction involve?
One metal kicking another metal out of a compound (reactive metal into solution of a dissolved metal compound)
What is the rule for a displacement reaction?
A more reactive metal will displace (and replace) a less reactive metal from its compound
Describe a displacement reaction
It’s always the metal ions that gain electrons and get reduced
The metal atom always loses electrons and is oxidised
What is the rusting of iron?
A redox reaction
When does rusting happen?
When the irons in contact with both oxygen and water
What is rust?
Hydrated iron (111) oxide
What is the word equation for rusting of iron?
Iron + oxygen + water = hydrated iron
(111) oxide
What happens in the rusting of iron?
Iron loses electrons when it reacts with oxygen (each iron atom loses three electrons) - oxidised
Oxygen gains electrons when it reacts with iron (each oxygen atom gains two electrons) - reduced
Describe metals being combined with other things to prevent rust
Iron can be mixed with other metals to prevent rust (alloy)
Eg Steels are alloys of iron and Carbon
- stainless steel is iron Carbon and chromium - it’s rustproof
Give some examples of preventing rusting by coating the iron with a barrier
Keeps out water, oxygen or both
Painting - ideal for large and small structures
Oiling or greasing is used when moving parts are involved (bike chains)
Describe a tin coating preventing rusting
tin plated
Tin acts as barrier stopping oxygen and water from reaching the surface of the iron
Only works if the tin remains intact (not scratched)
If tin scratched iron will lose electrons in preference to tin (because tin is less reactive than iron) and it will rust even faster than if it was on its own
What is the sacrificial method?
Placing a more reactive metal with the iron to prevent rusting - water and oxygen react with this and not the iron
Give two examples of the sacrificial method
Galvanising - coat of zinc - zinc is more reactive so loses electrons in preference to iron and acts as a barrier
Blocks of metal (magnesium) bolted to iron - used on hulls of ships or underground iron pipes
What does electrolysis mean?
Splitting up with electricity
Describe electrolysis
Electric current passed through a molten or dissolved ionic compound causing it to decompose
Creates flow of charge through electrolyte
As ions gain or lose electrons at cathode or anode they become atoms or molecules and are discharged from the solution
What happens at the cathode in electrolysis?
Positive ions move towards cathode and gain electrons
What happens at the anode in electrolysis?
Negative ions move towards anode and lose electrons
What can happen in the electrolysis of aqueous solutions?
Aqueous solutions contain ions from the water as well as ions from the solute (ionic compound)
Sometimes it’s easier to discharge the ions from the water instead of the ones from the solute depending on how easily the ions lose or gain electrons
What is produced at the anode and cathode in the electrolysis of aqueous sulfuric acid?
Hydrogen gas at cathodes
Oxygen at anode
What is produced at the anode and cathode during the electrolysis of Aquila sodium hydroxide solution?
Cathode - hydrogen gas
Anode- oxygen
What can copper (11) sulphate be electrolysed to form?
Copper and oxygen
What happens in the electrolysis of copper (11) sulfate solution when you use Carbon dioxide?
The cathode starts off as a piece of carbon but gets coated with a layer of copper (because copper ions are easier to discharge than hydrogen ions) - reduced
At the anode the hydroxide ions are discharged and converted into oxygen and water - oxidised
Which is the negative electrode?
Cathode
Which is the positive electrode?
Anode
What is the ionic equation for the reaction at the cathode in the electrolysis of copper (11) sulfate solution?
Cu2+ + 2e- -> Cu
What is the ionic equation for the reaction at the anode during the electrolysis of copper (11) sulfate solution?
4OH- - 4e- -> O2 + 2H2O
What happens in the electrolysis of molten ionic compounds?
Broke up into their elements
Positive metal ions are reduced to atoms at the cathode
Negative ions are oxidised to atoms at the anode
Why can molten ionic compounds be electrolysed?
Because the ions can move more freely
What is the solution that you electrolysed called?
Electrolyte
How do you increase the number of electrons transferred in electrolysis?
Electrolysing for a longer time
Increasing the current
What does increasing the amount of electrons transferred mean in electrolysis?
More product is produced
What is the amount of product produced in electrolysis proportional to?
Directly proportional to the time taken and current used
What is the amount of charge (Q- coulombs) flowing through a circuit in electrolysis equal to?
Current (I) multiplied by time (s)
Q=It
What equation can you use to work out the amount of product formed in electrolysis?
Q=It
When is it a redox reaction?
If electrons are transferred
What do fuel cells use to make electricity?
Hydrogen and oxygen
What do hydrogen and oxygen do when they react?
Give out energy
What kind of reaction is the one between hydrogen and oxygen?
Exothermic - releases energy
What does it mean when a reactions exothermic?
Less energy is taken to break bonds than is released in making bonds
What is a fuel cell?
An electrical cell that’s supplied with a fuel and oxygen ad uses energy from the reaction between them to produce electrical energy efficiently
What does hydrogen-oxygen fuel cell do?
Combines hydrogen and oxygen to release heat energy and water - no nasty pollutants
What reaction do hydrogen-oxygen fuel cells involve?
A redox reaction
What electrolyte is used in a hydrogen-oxygen fuel cell?
Potassium hydroxide
What electrodes are used in a hydrogen-oxygen fuel cell?
Porous Carbon with a catalyst
What happens at the cathode in a hydrogen-oxygen fuel cell?
Oxygen gains electrons (reduction) and reacts with water to make OH-
O2 + 4e- + H2O -> 4OH-
What happens at the anode in a hydrogen-oxygen fuel cell?
Hydrogen (loses electrons - oxidation) combines with hydroxide ions to produce water and electrons
2H2 + 4OH- -> 4H2O + 4e-
How does a hydrogen-oxygen fuel cell make electricity?
The electrons released by the hydrogen gas at the anode flow through an external circuit from the anode to the cathode (to react with oxygen) creating the electric current
What is the overall reactions equation in a hydrogen-oxygen fuel cell?
Hydrogen + oxygen -> water
2H2 + O2 -> 2H2O
What are the advantages of hydrogen-oxygen fuel cells?
Much more efficient than power stations or batteries (efficiency can be 80%)
Electricity generated directly from the reaction (direct energy transfer) so no turbines or generators
Aren’t a lot of stages so fewer places for energy to be lost
No moving parts so energy isn’t lost as friction
Only product is water - no pollution
What are the disadvantage s of hydrogen-oxygen fuel cells?
Producing hydrogen needed requires a lot of energy - may have come from burning fossil fuels - pollution
Often contain poisonous catalysts which eventually have to be disposed of - takes time and money and can cause environmental problems
Where are hydrogen-oxygen fuel cells used?
To provide electrical power in spacecraft
Why are hydrogen-oxygen fuel cells used in space craft?
Hydrogen and oxygen readily available from the rocket fuel tanks Lightweight and compact No moving parts that could go wrong The product is used as drinking water No other waste products to get rid of
Why is the car industry developing fuel cells?
Replace conventional petrol/Diesel engines
Fuel cells don’t produce pollution - good for cities with air pollution issues
Hydrogen can be obtained from decomposing water so large amount available
What are CFCs?
Chlorofluorocarbons
Organic molecules containing Carbon, chlorine and fluorine
What are the advantages of CFCs?
Non-toxic Non-flammable Chemically inert Insoluble in water Low boiling points -ideal for many uses
What were CFCs used in?
Coolants in refrigerators and air conditioning systems
Propellants in aerosols
When did scientists discover that chlorine helps destroy ozone?
1974
When did scientists find evidence of decreasing ozone levels over Antarctica?
1985
What supports the hypothesis that CFCs destroy ozone?
High levels of compounds produced by the breakdown of CFCs in the upper atmosphere
What is ozone?
A form of oxygen (O3 - three oxygen atoms) that is in the stratosphere in the ozone layer
What does ozone do?
Absorbs ultraviolet light from the sun
Absorbs UV light and breaks down into oxygen molecule and an oxygen atom
O3 + UV -> O + O2
Oxygen molecule and oxygen atom join to make ozone again
O + O2 -> O3
Natural balance
What does reducing the amount of ozone in the stratosphere cause?
More UV light hitting the surface of the earth
Increased risk of sunburn and skin cancer
Which countries banned CFCs as aerosol propellants in 1978?
USA
Canada
Sweden
Norway
What happened after the ozone hole was discovered?
Many countries got together and decided to reduce CFC production and eventually ban them altogether
How are free radicals made?
By breaking covalent bonds evenly so each atom gets one of the shared electrons making the free radical very, very reactive because of the unpaired electron (unpaired electron showed by dot •)
What does UV light do to the Carbon-chlorine bonds in CFCs?
Break to form free radicals
Only happens in the stratosphere where UV light is stronger
What is the equation for the breaking up of CFCs?
CCl2F2 -> CClF2• + Cl•