C4 - Chemical Changes Flashcards
What is the pH scale
A scale going from 1 - 14 which measures how acidic or alkaline a solution is.
The lower the pH of a solution, the more acidic it is
The higher the pH of a solution, the more alkaline it is
A neutral substance (e.g. pure water) is pH 7
Give some examples of these pH scales:
a) pH 1
b) pH 3
c) pH 4
d) pH 5-6
e) pH 7
f) pH 8-9
g) pH 9-10
h) pH 11
i) pH 12-13
j) pH 13-14
a) Car battery acid, stomach acid
b) vinegar, lemon juice
c) acid rain
d) normal rain
e) pure water
f) washing-up liquid
g) pancreatic juice
h) sop powder
i) bleach
j) caustic soda (drain cleaner)
Give 2 ways to measure the pH of a solution
Universal indicator
A pH probe attached to a pH meter
What is an indicator (that measures pH)?
A dye that changes colour depending on the pH. Some indicators contain a mixture of dyes that mean they can gradually change colour over a broad range of pH. These are called wide range indicators and they’re useful for estimating the pH of a solution
acid + base —->
salt + water
It is a neutralisation reaction
(for example, H+ + OH- —> H2O
What do acids and bases combine to make?
A salt + a water, it is a neutralisation reaction
Acids produce what in water?
Protons. They ionise in aqueous - so they produce hydrogen ions (H+), which is just a proton as it has lost its only electron
What is the difference between strong acids and weak acids?
Strong acids ionise completely in water. All acid particles dissociate to release protons
Weak acids do not ionise fully in a solution. Only a small proportion of acid particles dissociate to release H+ ions or protons
The ionisation of a weak acid is a reversible reaction, which sets up an equilibrium reaction.
Give the formulas for the strong acid hydrochloric acd and the weak acid carbonic acid I think ionising in water
Strong = HCl ---> H+ + Cl- Weak = CH3COOH H+ + CH3COO-
Give some examples of
a) Strong acids
b) Weak acids
a) Hydrochloric acid (stomach acid), sulfuric acid, nitric acid
b) Ethanoic acid, citric acid, carbonic acid
Reactions of acids involve H+ ions reacting with other substances. If the concentration of H+ ions is higher, what will happen to the rate of reaction?
It will be faster, so strong acids will be more reactive when ionising in water than weak acids will be when ionising in water
pH is a measure of what?
The concentration of Hydrogen ions
For every decrease of on the pH scale, the concentration of H+ ions increases by a factor 10
What factor does every decrease of 1 on the pH scale mean in terms of hydrogen ions?
For every decrease of on the pH scale, the concentration of H+ ions increases by a factor 10
Strong acids and concentrated acids are concentrated acids. True or false?
False - Acid strength tells you what proportion of acidic molecules ionise in water
Concentrated acids is to do with how much acid is within a certain volume of water. The more acid in a concentrated volume, the more concentrated it is
pH will decrease with increasing acid concentration regardless of whether it’s strong or weak. True or false?
True
Acid + metal oxide —>
Salt + water
Acid + metal hydroxide —>
Salt + water
Will bases that don’t dissolve in water still take part in the neutralisation reaction with acids?
Yes
Some metal oxide and metal hydroxides dissolve in water. These soluble compounds are what?
Alkalis
Acid + metal carbonate —>
Salt + water + carbon dioxide
Hydrochloric acid +
a) copper oxide —>
b) sodium carbonate —>
a) Copper chloride + water
(this follows acid + metal oxide –> salt + water)
b) Sodium chloride + water + carbon dioxide
(this follows acid + metal oxide —> salt + water + CO2)
How can you make soluble salts?
With an insoluble base - you need to choose the right acid and insoluble base, such as an insoluble metal oxide, hydroxide or carbonate. E.g. if you want to make copper chloride, you could mix hydrochloric acid and copper oxide
CuO + HCl —> CuCl2 + H2O
Balance the equation
CuO + 2HCl —> CuCl2 + H2O
Makes a soluble salt with an insoluble base
Rearrange the instructions for the practical of making a soluble salt from an insoluble salt:
1) Then filter out the excess solid to get the salt solution with a funnel and filter paper into a conical flask
2) You need to choose the right acid and insoluble base, such as an insoluble metal oxide, hydroxide or carbonate. E.g. if you want to make copper chloride, you could mix hydrochloric acid and copper oxide
3) To get pure, solid crystals of the salt, gently heat the solution using a water bath or an electric heater to evaporate some of the water (to make it more concentrated) and then stop heating it and leave the solution to cool. Crystals out of the salt should form, which can be filtered out of the solution then dried. This is called crystallisation
4) Gently warm the dilute acid using a Bunsen burner, then turn it off
5) Add the insoluble base a bit at a time, until no more reacts (so the base is in excess). You’ll know when all the acid has been neutralised because, even after stirring, the excess solid will just sink to the bottom without reacting
2) You need to choose the right acid and insoluble base, such as an insoluble metal oxide, hydroxide or carbonate. E.g. if you want to make copper chloride, you could mix hydrochloric acid and copper oxide
4) Gently warm the dilute acid using a Bunsen burner, then turn it off
5) Add the insoluble base a bit at a time, until no more reacts (so the base is in excess). You’ll know when all the acid has been neutralised because, even after stirring, the excess solid will just sink to the bottom without reacting
1) Then filter out the excess solid to get the salt solution with a funnel and filter paper into a conical flask
3) To get pure, solid crystals of the salt, gently heat the solution using a water bath or an electric heater to evaporate some of the water (to make it more concentrated) and then stop heating it and leave the solution to cool. Crystals out of the salt should form, which can be filtered out of the solution then dried. This is called crystallisation
Give the reactivity series from their symbols
K, Na, Li, Ca, Mg, C, Zn, Fe, H, Cu
Potassium Sodium Lithium Calcium Magnesium Carbon Zinc Iron Hydrogen Copper
Give the reactivity series from most - least reactive
Potassium Sodium Lithium Calcium Magnesium Carbon Zinc Iron Hydrogen Copper
For metals, how is their reactivity measured?
How easily they lose electrons, forming positive ions The higher up the reactivity series a metal is, the mroe easily they form positive ions Potassium Sodium Lithium Calcium Magnesium Carbon Zinc Iron Hydrogen Copper