C2.1/2 - Structure and Bonding Flashcards

1
Q

What is a compound?

A

Compounds are substances in which atoms of two or more elements are chemically combined.

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2
Q

Why do atoms take part in chemical bonding?

A

Atoms take part in chemical bonding in order to achieve the electronic structure of a noble gas (full outer energy level).

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3
Q

When an atom loses an electron, what charge does the remaining ion have?

A

When an atom loses an electron, the remaining ion has a positive charge.

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4
Q

When an atom gains an electron, what charge does the remaining ion have?

A

When an atom gains an electron, the remaining ion has a negative charge.

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5
Q

What is the electronic structure of an ion?

A

Ions have the electronic structure of a noble gas (Group 0).

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6
Q

What do we call the elements in Group 1?

A

The elements in Group 1 are called the Alkali metals.

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7
Q

When Group 1 metals react with non-metal elements, what type of ion is formed?

A

When Group 1 metals react with non-metal elements, the Group 1 element forms an in with a single positive charge.

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8
Q

What do we call the elements in Group 7?

A

The elements in Group 7 are called the Halogens.

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9
Q

When Group 7 elements react with the alkali metals, what charge does the halide ion gain?

A

When Group 7 elements react with alkali metals, the halide ion has a negative charge.

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10
Q

What type of bonding happens when atoms share pairs of electrons?

A

When atoms share pairs of electrons, this is called covalent bonding.

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11
Q

What do we call covalent molecules with only a small number of atoms, such as H2, Cl2, O2, HCl, H20, NH3 and CH4?

A

Covalent molecules with only a small number of atoms are called simple molecules.

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12
Q

What are the melting and boiling points of simple molecules and why?

A

Simple molecules have low melting and boiling points due to the weak intermolecular forces between the molecules.

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13
Q

Why do simple molecules not conduct electricity?

A

Simple molecules do not conduct electricity as the molecules do not have an overall electric charge.

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14
Q

Why do ionic compounds have high melting and boiling points?

A

Ionic compounds have high melting and boiling points as there are strong electrostatic forces between oppositely charged ions.

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15
Q

Why do solid ionic compounds not conduct electricity?

A

Solid ionic compounds cannot conduct electricity because the ions are not free to move.

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16
Q

Why do ionic compounds conduct electricity when they are melted or dissolved in water?

A

Ionic compounds can conduct electricity when melted or dissolved in water because now the ions are free to move.

17
Q

What type of molecules are diamond, graphite and silicon dioxide?

A

Diamond, graphite, and silicon dioxide are giant covalent lattices (macromolecules).

18
Q

Why do giant covalent structures have very high melting points?

A

Giant covalent structures have very high melting points as all the atoms are linked to other atoms by strong covalent bonds.

19
Q

Diamond and graphite are formed from which element?

A

Diamond and graphite are formed from carbon.

20
Q

What is the structure of silicon dioxide?

A

Each silicon atom is covalently bonded to four oxygen atoms.

Each oxygen atom is covalently bonded to two silicon atoms.

21
Q

What is the structure of diamond?

A

Each carbon atom forms four covalent bonds.

22
Q

What is the structure of graphite?

A

Each carbon atom forms three covalent bonds.

23
Q

Why is diamond very hard?

A

Diamond is very hard because each carbon atom forms four strong covalent bonds.

24
Q

Why is graphite soft and slippery?

A

Graphite is soft and slippery because it consists of layers.

There are no covalent bonds/weak intermolecular forces between the layers so they are free to slide.

25
Q

Why is graphite a good conductor of heat and electricity?

A

In graphite, one electron from each carbon atom is delocalised. The free electrons allow graphite to conduct heat and electricity as they can move and carry energy.

26
Q

What is the structure of fullerenes?

A

Fullerenes consist of hexagonal rings of carbon atoms.

27
Q

What are fullerenes used in?

A

Fullerenes have uses such as lubricants and in nanotubes.

28
Q

Why are metals good conductors of heat and electricity?

A

Metals are good conductors of heat and electricity because they have delocalised electrons that can move.

29
Q

Why can metals be bent and shaped?

A

Metals can be bent and shaped because the layers of atoms in metals are able to slide over each other. The atoms are of the same size.

30
Q

What are alloys?

A

Alloys are usually made from two or more metals or other elements joined to metals to make them stronger.

31
Q

Why are alloys harder than pure metals?

A

Alloys are harder than pure metals because the different sized atoms distort the layers so it is difficult for them to slide over each other.

32
Q

What are shape memory alloys?

A

Shape memory alloys can return to their original shape after being deformed, usually by heating (nitinol/dental braces)

33
Q

What conditions can we change to alter the properties of a polymer?

A

To alter the properties of a polymer, we can change the temperature of the reaction or use a different catalyst (to produce high-density poly(ethene) or low-density poly(ethene).

34
Q

What is a thermosoftening polymer?

A

Thermosoftening polymers consist of individual tanlged polymer chains. When we heat them, these polymers melt and can be reshaped.

35
Q

What is meant by a thermosetting polymer?

A

Thermosetting polymersconsist of polymer chains with covalent cross-links between them. They do not melt when they are heated.

36
Q

In terms of intermolecular forces, why can thermosoftening polymers melt when heated?

A

Thermosoftening polymers have weak intermolecular forces between the chains. They are easily broken, hence the polymer can melt easily.

37
Q

What are nanoparticles?

A

Nanoparticles are between 1-100nm in size. They consist of a few hundred atoms.

38
Q

Why are nanoparticles useful?

A

Nanoparticles are useful because they have a high surface area to volume ratio.