C2 BONDING, STRUCTURE AND THE PROPERTIES OF MATTER Flashcards
what is ionic bonding?
electrostatic attraction between positive and negative ion
how are ionic compounds held together?
giant lattice
regular structure that extends in all directions in a substance
properties of ionic compound?
high melting and boiling point
does not conduct electricity when solid (ions in fixed position)
conduct when molten or dissolved in water - ions are free to move
how are ionic compounds formed? explain in terms of MgO case
reaction of a metal with a non metal
electron transfer occurs - metal gives away its outer shell electron to non-metals.
Mg is in group 2 so have two available outer shell electrons.
O is in group 6 and can accept 2 electrons on its outer shell electron to get full outer shell confiigurations.
mg becomes mg2+ and o becomes o2- (oxide)
covalent bond?
shared pair of electrons between two atoms
structure and properties of simple molecular covalent substances?
does not conduct electricity
small molecules
weak intermolecular forces
low melting and boiling point
how do intermolecular forces change as the mass/size of the molecule increases?
they increase (that causes melting/boiling point to increase as well).
more energy is needed to overcome these forces
polymers?
very large molecules with atoms linked by covalent bonds
giant covalent substances?
solid , atoms covalently bonded together in a giant lattice.
high melting/boiling points - strong covalent bonds
mostly don’t conduct electricity (no delocalised e-)
e.gs - diamond, graphite, silicon dioxide
describe and explain the property of diamond (allotropes of carbon) ?
four strong covalent bonds for each carbon atom
very hard
very high melting point
does not conduct electricity
describe and explain the property of graphite(allotropes of carbon) ?
•3 covalent bonds for each carbon atom
•layers of hexagonal rings
•high melting point
•layers free to slide (weak intermolecular forces between layers; soft)
•can be used as lubricant
conduct thermal and electricity due to one delocalised electron per each carbon atoms
describe and explain the property of fullerenes(allotropes of carbon) ?
hollow shaped molecule
based on hexagonal rings but may have 5-7 carbon rings
c60 has a spherical shape , simple molecular structure (buckministerfullerene)
describe and explain the property of nanotubes (allotropes of carbon)
cylindrical fullerene with high length to diameter ratio
high intensile strength (strong bonds)
conductivity (deloc. electrons)
describe and explain the property of graphene (allotropes of carbon)
a single layer of graphite
metallic bonding?
forces of attraction between delocalised electrons and nuclei of metal ions